Novel synthesis of fluoroalkylated α,β-unsaturated ketones by the oxygenative perfluoroalkylation of α-chlorostyrenes

Chemistry Letters

Volumn , Issue 7, 2000, Pages 804-805

  Yoshida, Masato ^a   Ohkoshi, Masanori ^a   Iyoda, Masahiko ^a  

^a TOKYO METROPOLITAN UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0034339585     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2000.804     Document Type: Article

References (11)

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5. In this reaction, the saturated ketone 4a was produced at first, and then the elimination of HF from 4a occurred to give the unsaturated ketone 2a. The ketone 3a should be produced by the photoisomerization of 2a. When the isolated 2a was irradiated in benzene under similar conditions, the isomerization from 2a to 3a was observed; the ratio of 2a / 3a in photostationary state was 1 / 4.
6. 13O 438.0289.
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