Facile synthesis of optically active homocysteine from methionine

Chemistry Letters

Volumn , Issue 5, 2000, Pages 468-469

  Shiraiwa, Tadashi ^a   Nakagawa, Kazuo ^a   Kanemoto, Norito ^a  

^a KANSAI UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0034335681     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2000.468     Document Type: Article

References (13)

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5. Y. Akiyama, Y. Aoki, and H. Nohira, Symposium on Molecular Chirality '99, Sendai, May 1999, Abstr., No. PS-28.
6. C. A. Dekker and J. S. Fruton, J. Biol. Chem., 173, 471 (1948).
7. M. D. Armstrong and J. D. Lewis, J. Org. Chem., 16, 74 (1951).
8. 4S: C, 31.65; H, 4.43; N, 6.15%.
9. 4
10. 2-), 3.26-3.15 (1H, m), 3.05-2.97 (1H, m), 2.73-2.64 (1H, m), 2.6-2.5 (m), 2.3-2.4 (m), 2.13-1.97 (1H, m). The IR spectrum was idential to that of (2S)-TDC·HCl from L-Met.
11. 1S: C, 35.54; H, 6.71: N, 10.36%.
12. 13C NMR and IR spectra were virtually identical to those of (4S)-TDC·HCl.
13. 13C NMR and IR spectra were virtually identical to those of L-Hcy.