Oxidation of cycloalkanes with potassium peroxosulfate catalyzed by montmorillonite-immobilized metal tetrapyridylporphyrin complexes

Petroleum Chemistry

Volumn 40, Issue 6, 2000, Pages 391-398

  Avdeev, M V ^a   Bagrii, E I ^a   Maravin, G B ^a   Korolev, Yu M ^a   Borisov, R S ^a  

^a TOPCHIEV INSTITUTE OF PETROCHEMICAL SYNTHESIS   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

ADAMANTANE DERIVATIVE; CYCLOALKANE; IRON COMPLEX; MANGANESE DERIVATIVE; METAL COMPLEX; MONTMORILLONITE; OCTANE; PORPHYRIN DERIVATIVE; POTASSIUM DERIVATIVE; SILICATE; TITANIUM DERIVATIVE;

ADSORPTION; ALKYLATION; ARTICLE; DISSOLUTION; MOLECULAR STABILITY; OXIDATION; REACTION ANALYSIS;

EID: 0034334942     PISSN: 09655441     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (9)

1. Shilov, A.E., Activation and Functionalization of Alkanes, Hill, C.L., Ed., New York: Wiley-Interscience, 1989. Translated under the title Aktivatsiya i kataliticheskie reaktsii alkanov Moscow: Mir, 1992, p. 2.
2. Shilov, A.E. and Shul'pin, G.B., Aktivatsiya i kataliticheskie reaktsii uglevodorodov (Activation and Catalytic Reactions of Hydrocarbons), Purmal', A.P., Ed., Moscow: Nauka, 1995, p. 307.
3. Maravin, G.B., Avdeev, M.V., and Bagrii, E.I., Oxidative Functionalization of Saturated Hydrocarbons on Porphyrin Metal Complex Catalysts, Neftekhimiya, 2000, vol. 40, no. 1, p. 3 [Pet. Chem. (Engl. Transl.), 2000, vol. 40, no. 1, p. 1].
4. Groves, J.T. and Kruper, W.J., Preparation and Characterization of an Oxoporphyrinatochromium(V) Complex, J. Am. Chem. Soc., 1979, vol. 101, no. 25, p. 7613.
5. Traylor, T.G. and Tsuchiya, S., Perhalogenated Tetraphenylhemins: Stable Catalysts of High Turnover Catalytic Hydroxylations, Inorg. Chem., 1987, vol. 26, no. 8, p. 1338.
6. Traylor, P.S., Dolphin, D., and Traylor, T.G., Sterically Protected Hemins with Electronegative Substituents: Efficient Catalysts for Hydroxylation and Epoxidation, J. Chem. Soc., Chem. Commun., 1984, no. 5, p. 279.
7. Barloy, L., Battioni, P., and Mansuy, D., Manganese Porphyrins Supported on Montmorillonite as Hydrocarbon Mono-oxygenation Catalysts: Particular Efficacy for Linear Alkane Hydroxylation, J. Chem. Soc., Chem. Commun., 1990, no. 19, p. 1365.
8. Khalfallah, K., Boudalli, Synthesis and Characterization of Titanium Pillared Montmorillonites, Microporous Mater., 1994, private communication.
9. Solovieva, A.B., Polymer Sulfofluoride Films as Carriers for Metalloporphyrin Catalysts, React. Polym., 1991, vol. 16, no. 1, p. 9.