Mechanistic modeling of the thermal cracking of tetralin

Industrial and Engineering Chemistry Research

Volumn 39, Issue 11, 2000, Pages 4152-4165

  Bounaceur, Roda ^a   Scacchi, Gérard ^a   Marquaire, Paul Marie ^a   Dominé, Florent ^b  

^a Dept de Chim Phys des Reactions ^*  (France)

^b Carbochem   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; CRACKING (CHEMICAL); DEHYDROGENATION; FREE RADICAL REACTIONS; IMPURITIES; MATHEMATICAL MODELS; REACTION KINETICS; THERMAL EFFECTS;

BUTYLBENZENE; METHYLINDANE; TETRALIN; THERMAL CRACKING;

AROMATIC HYDROCARBONS;

TETRALIN DERIVATIVE;

ARTICLE; CHEMICAL REACTION KINETICS; HYDROGENATION; PHYSICAL CHEMISTRY; PROTON TRANSPORT; PYROLYSIS;

EID: 0034332749     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie000276f     Document Type: Article

References (17)

1. McMillen, D. F.; Malhotra, R.; Chang, S.; Ogier, W. C.; Nigenda, S. Mechanisms of Hydrogen Transfer and Bond Scission of Strongly Bonded Coal Structures in Donor-Solvent System. Fuel 1987, 66, 1611-1620.
2. Curran, G. P.; Struck, R. T.; Gorin, E. Mechanism of Hydrogen-Transfer Process to Coal and Coal Extract. Ind. Eng. Chem. Process Des. Dev. 1967, 6, 166-173.
3. Vernon, L. W. Free-Radical Chemistry of Coal Liquefaction: Role of Molecular Hydrogen. Fuel 1980, 59, 102-106.
4. De Viegler, J.; Antonius, P.; Kieboom, P.; van Bekkum, H. Behavior of Tetralin in Coal Liquefaction. Fuel 1984, 63, 334-340.
5. Song, C.; Lai, W. C.; Schobert, H. H.; Hydrogen-Transferring Pyrolysis of Long-Chain Alkanes and Thermal Stability Improvement of Jet Fuels by Hydrogen Donors. Ind. Eng. Chem. Res. 1994, 33, 548-557.
6. Yoon, E. M.; Selvaraj, L.; Song, C.; Stallman, J. B.; Coleman, M. M. High-Temperature Stabilizers for Jet Fuels and Similar Hydrocarbon Mixtures. 1. Comparative Studies of Hydrogen Donors. Energy Fuels 1996, 10, 806-811.
7. Poutsma, M. L. Free-Radical Thermolysis and Hydrogenolysis of Model Hydrocarbons Relevant to Processing of Coal. Energy Fuels 1990, 4, 113-131.
8. Hooper, J. R.; Hendrik, A. J.; Battaerd, J.; Evans, D. G. Thermal dissociation of Tetralin between 300 and 450°C. Fuel 1978, 58, 132-138.
9. Yen, Y. K.; Furlani, D. E.; Weller, S. W. Batch Autoclave Studies of Catalytic Hydrodesulfurization of Coal. Ind. Eng. Chem. Prod. Res. Dev. 1976, 15, 24.
10. Grigor'eva, E. N.; Panchenko, S. S.; Korbkov, V. Yu.; Kalechits, I. V. The Kinetics of Tetralin Thermolysis at 450-510 °C. Solid Fuel Chem. 1991, 25, 2, 26-34.
11. Grigor'eva, E. N.; Panchenko, S. S.; Korbkov, V. Yu.; Kalechits, I. V. Main Reactions and Intermediates of Liquid-Phase Tetralin Thermolysis. Solid Fuel Chem. 1991, 25, 4, 103-107.
12. Grigor'eva, E. N.; Panchenko, S. S.; Korbkov, V. Yu.; Kalechits, I. V. Kinetic Model of Liquid-Phase Thermolysis of Tetralin. Solid Fuel Chem. 1991, 25, 6, 101-106.
13. Khorasheh, F.; Gray, M. R. High-Pressure Thermal Cracking of n-Hexadecane in Tetralin. Energy Fuels 1993, 7, 6, 960-967.
14. Frantz, J. A.; Camaioni, D. M.; Beishline, R. R.; Dalling, D. K. Products, Radical Intermediates, and Hydrogen Production in the Thermal Decomposition of 1,2-Dihydronaphthalene. J. Org. Chem. 1984, 49, 3563-3570.
15. McMillen, D. F.; Malhotra, R.; Hum, G. P.; Chang, S. Hydrogen-Transfer-Promoted Bond Scission Initiated by Coal Fragments. Energy Fuels 1987, 1, 193-198.
16. McMillen, D. F.; Malhotra, R.; Nigenda, S. E. The Case for Induced Bond Scission during Coal Pyrolysis. Fuel 1989, 68, 380-386.
17. Savage, P. E.; Jacobs, G. E.; Javanmardian, M. Autocatalysis and Aryl-Alkyl Bond Cleavage in 1-Dodecylpyrene Pyrolysis. Energy Fuels 1989, 28, 645-654.