A time-resolved study of the mechanism of the energy transfer from a ligand to the lanthanide(III) ion in solutions and solid films

Luminescence

Volumn 15, Issue 6, 2000, Pages 341-350

  Lemmetyinen, H ^a   Vuorimaa, E ^a   Jutila, A ^b   Mukkala, Veli Matti ^c   Takalo, Harri ^d   Kankare, Jouko ^e  

^a TAMPERE UNIVERSITY OF TECHNOLOGY   (Finland)

^b UNIVERSITY OF HELSINKI   (Finland)

^c Wallac Oy   (Finland)

^d Innotrac Diagnostics Oy   (Finland)

^e UNIVERSITY OF TURKU   (Finland)

Author keywords

Intramolecular energy transfer; Life times; Quantum yields; Time resolved study

Indexed keywords

ENERGY TRANSFER; EUROPIUM COMPOUNDS; GADOLINIUM COMPOUNDS; LUMINESCENCE; PYRIDINE; QUANTUM YIELD; RARE EARTH ELEMENTS; RATE CONSTANTS; TERBIUM COMPOUNDS;

IMMUNOHISTOCHEMISTRY; INTRAMOLECULAR ENERGY TRANSFER; LANTHANIDE CHELATES; LANTHANIDE(III) IONS; LIFE-TIMES; PHENYLETHYNYL; PHOTOCHEMICAL PROPERTIES; SOLID FILMS; TIME RESOLVED STUDIES;

IONS;

CHELATING AGENT; LANTHANIDE; LIGAND;

ARTICLE; CHEMISTRY; ENERGY TRANSFER; LUMINESCENCE; PHOTOCHEMISTRY; SOLUTION AND SOLUBILITY; SPECTROFLUOROMETRY;

CHELATING AGENTS; ENERGY TRANSFER; LIGANDS; LUMINESCENCE; METALS, RARE EARTH; PHOTOCHEMISTRY; SOLUTIONS; SPECTROMETRY, FLUORESCENCE;

EID: 0034331586     PISSN: 15227235     EISSN: None     Source Type: Journal    
DOI: 10.1002/1522-7243(200011/12)15:6<341::aid-bio625>3.0.co;2-1     Document Type: Article

References (38)

1. 0 lifetime in europium Tris(2,2,6,6-tetramethyl-3,5-heptanedinato). J. Phys. Chem. 1996; 2: 9216-1922.
2. Sato S, Wada M. Relations between intramolecular energy transfer efficiencies and triplet state energies in rare earth β-diketone chelates. Bull. Chem. Soc. Jpn. 1970; 43: 1955-1962.
3. Takalo H, Hänninen E, Kankare J. Luminescence of europium(III) chelates with 4-(arylethynyl)pyridines as ligands. Helv. Chim. Acta 1993; 76: 877-883.
4. Hemmilä I, Mukkala VM, Iatva M, Kiilholma P. Di- and tetracarboxylate derivatives of pyridines, bipyridines and terpyridines as luminogenic reagents for time-resolved fluorometric determination of terbium and dysprosium. J. Biochem. Biophys. Methods 1993; 26: 283-290.
5. 3- in hydroxylic solution. Chem. Phys. Lett. 1993; 216: 241-245.
6. Dakubu S, Hale R, Lu A, Quick J, Solas D, Weinberg J. Time-resolved pulsed fluorescence immunometric assays of carcinoembryonic antigen. Clin. Chem. 1988; 34: 2337-2340.
7. Mukkala VM, Kankare J. New 2,2′-bipyridine derivatives and their luminescence properties with europium(III) and terbium(III) Ions. Helv. Chim. Acta 1992; 75: 1578-1592.
8. Buntinx G, Naskrecki R, Poizat O. Subpicosecond transient absorption analysis of the photophysics of 2,2′-Bipyridine and 4,4-Bipyridine in Solution. J. Phys. Chem. 1996; 100: 19380-19388.
9. Mukkala VM, Helenius M, Hemmilä I, Kankare J, Takalo H. Development of luminescent europium(III) and terbium(III) chelates of 2,2′:6′,2″-terpyridine derivatives for protein labelling. Helv. Chim. Acta 1993; 76: 1361-1378.
10. Mukkala VM, Sund C, Kwlatkowski M, Pasanen P, Högberg M, Kankare J. New heteroatomic complexing agents and luminescence of their europium(III) and terbium(III) chelates. Helv. Chim. Acta 1992; 75: 1621-1632.
11. Saha AK, Kross K, Kloszewski ED, Upson DA, Toner JL, Snow RA, Black CDV, Desai VC. Time-resolved fluorescence of a new europium chelate complex; demonstration of highly sensitive detction of protein and DNA samples. J. Am. Chem. Soc. 1993; 115: 11032-11033.
12. Mukkala VM, Liitti P, Hemmilä I, Takalo H, Matachescu C, Kankare J. Novel thiazole-containing complexing agents and luminescence of their europium(III) and terbium(III) chelates. Helv. Chim. Acta 1996; 79: 295-306.
13. Remuinan MJ, Roman H, Teresa Aionso M, Rodriguez-Ubis JC. Synthesis and luminescence properties of europium(III) and terbium(III) complexes with polyacid chelates derived from 2,6-bis-(N-pyrazolyl)pyridine. J. Chem. Soc. Perkin Trans. 1993; 2: 1099-1102.
14. Takalo H, Mukkala VM. PCT Appl./F191/00373, 1991.
15. Alpha B, Lehn JM, Mathis G. Energy transfer luminescence of europium(III) and terbium(III) cryptates of macrobicyclic polypyridine ligands. Angew. Chem. Int. Ed. Engl. 1987; 26: 266-267.
16. 3+ cryptate: a low-temperature solid-state study. J. Phys. Chem. 1998; 92: 2419-2422.
17. Sato N, Shinkai S. Energy-transfer luminescence of lanthanide ions encapsulated in sensitizer-modified calix[4] arenas. J. Chem. Soc. Perkin Trans. 1993; 2: 621-624.
18. 3+: the role of the counterions investigated. J. Phys. Chem. A 1997; 101: 2755-2765.
19. Steemers FJ, Verboom W, Reinboudt DN, van der Tol EB, Verhoeven JW. New sensitizer-modified calix[4] arenas enabling near-UV excitation of complexed luminescent lanthanide ions. J. Am. Chem. Soc. 1995; 117: 9408-9414.
20. Pikramenou Z, Nocera DG. Luminescent supramolecular architectures: a cyclodextrin modified with a europium(III) crown swing. Inorg. Chem. 1992; 31: 532-536.
21. 3+. Chem. Phys. Lett. 1986; 129: 541-545.
22. III ion luminescence and efficient energy transfer between lanthanide chelates within the polymeric structure in aqueous solutions. J. Chem. Soc. Perkin Trans. 1995; 2: 995-999.
23. Xu YY, Pettersson K, Blonberg K, Hemmilä I, Mikola H, Lövgren T. Simultaneous quadruple-label fluorometric immunoassay of thyroid-stimulating hormone, 17α-hydroxyprogesterone, immunoreactive trypsin, and creatine kinase MM isoenzyme in dried blood spots. Clin. Chem. 1992; 38: 2038-2043.
24. Latva M, Takalo H, Mukkala VM, Matachescu C, Rodriguez-Ubis JC, Kankare J. Correlation between the lowest triplet state energy level of the ligand and lanthanide(III) luminescence quantum yield. J. Lumin. 1997; 75: 149-169.
25. Takalo H, Pasanen P, Kankare J. Acta Chem. Scand., Set. B 1988; 42: 614.
26. III complexing agents and labels with 4-(phenyethynyl)pyridine subunits. Helv. Chim. Acta 1996; 79: 789-802.
27. Roberts G. Langmuir-Blodgett Films. Plenum: New York, 1990; 22.
28. 3- Phen. Thin Solid Films 1997; 295: 228-233.
29. 3Phen in LB films. Thin Solid Films 1997; 302: 223-230.
30. Lemmetyinen H, Ikonen M, Mikkola J. A kinetic atudy of monomer and excimer fluorescence of pyrene lecithin in Langmuir-Blodget films. Thin Solid Films, 1991; 204: 417-439.
31. 3+ cryptate: a low-temperature solid-state study. J. Phys. Chem. 1998; 92: 2419-2422.
32. Piguet C, Bünzli JCG, Bernardinelli G, Hopfgartner G, Petoud S, Schasd O. Lanthanide podates with predetermined structural and photophysical properties: strongly luminescent self-assembled heterodinuclear d-f complexes with a segmental ligand containing heterocyclic imines and carboxamide binding units. J. Am. Chem. Soc. 1996; 118: 6681-6697.
33. Tamai N, Yamazaki T, Yamazaki I. Picosecond dynamics of excitation-energy relaxation of dye molecules in Langmuir-Blodgett monolayers. Can. J. Phys. 1990; 68: 1013-1022.
34. Vuorimaa E, Ikonen M, Lemmetyinen H. Photophysics of rhodamine dimers in Langmuir-Blodgett films. Chem. Phys. 1984; 188: 289-302.
35. Yamazaki I, Tamai N, Yamazaki T. Electronic excitation transfer in organized molecular assemblies. J. Phys. Chem. 1990; 94: 516-525.
36. Tamai N, Matsuo H, Yamazaki T, Yamazaki I. Excitation energy relaxation of oxacyanine in Langmuir-Blodgett monolayer films: picosecond time-resolved fluorescence studies. J. Phys. Chem. 1992; 96: 6550-6554.
37. 0 lifetime in europium Tris(2,2,6,6-tetramethyl-3,5-heptanedinato). J. Phys. Chem. 1996; 2: 9216-9222.
38. Sabbatini N, Guardigli M, Lehn JM. Luminescent lanthanide complexes as photochemical supramolecular devices. Coord. Chem. Rev. 1993; 123: 201-228.