Kinetics of MnO2-catalyzed acetic acid oxidation in supercritical water

Industrial and Engineering Chemistry Research

Volumn 39, Issue 11, 2000, Pages 4014-4019

  Yu, Jianli ^a   Savage, Phillip E ^a  

^a UNIVERSITY OF MICHIGAN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACETIC ACID; CATALYSIS; CATALYSTS; MAGNESIA; REACTION KINETICS; SATURATION (MATERIALS COMPOSITION); SOLUTIONS; SUPERCRITICAL FLUIDS; WATER;

SATURATION KINETICS; SUPERCRITICAL WATER;

OXIDATION;

ACETIC ACID; MANGANESE DIOXIDE;

ARTICLE; CATALYSIS; CHEMICAL REACTION KINETICS; OXIDATION; REACTION ANALYSIS; REACTOR; STEADY STATE; SUPERCRITICAL FLUID CHROMATOGRAPHY; TEMPERATURE DEPENDENCE;

EID: 0034325840     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie000583l     Document Type: Article

References (19)

1. Modell, M. Supercritical water oxidation. In Standard Handbook of Hazardous Waste Treatment and Disposal; Freeman, H. M., Ed.; McGraw-Hill: New York, 1989; Section 8.11.
2. Barner, H. E.; Huang, C. Y.; Johnson, T.; Jacobs, G.; Martch, M. A. Supercritical water oxidation: an emerging technology. J. Hazard. Mater. 1992, 31, 1.
3. Ding, Z.; Frisch, M. A.; Li, L.; Gloyna, E. F. Catalytic oxidation in supercritical water. Ind. Eng. Chem. Res. 1996, 35, 3257.
4. Aki, S. N. V. K.; Abraham, M. A. An economic evaluation of catalytic supercritical water oxidation. Environ. Prog. 1998, 17, 246.
5. Martino, C. J.; Savage, P. E. Total organic carbon disappearance kinetics for the supercritical water oxidation of monosubstituted phenols. Environ. Sci. Technol. 1999, 33, 1911.
6. Wightman, T. J. Studies in Supercritical Wet Air Oxidation. M.S. Thesis, University of California at Berkeley, Berkeley, CA, 1981.
7. 2 in supercritical water oxidation of 2,4-dichlorophenol and acetic acid. J. Supercrit. Fluids 1990, 3, 249.
8. Boock, L. T.; Klein, M. T. Lumping strategy for modeling the oxidation of C1-C3 alcohols and acetic acid in high-temperature water. Ind. Eng. Chem. Res. 1993, 32, 2464.
9. Meyer, J. C.; Marrone, P. A.; Tester, J. W. Acetic acid oxidation and hydrolysis in supercritical water. AIChE J. 1995, 41, 2108.
10. Savage P. E.; Smith, M. A. Kinetics of acetic acid oxidation in supercritical water. Environ. Sci. Technol. 1995, 29, 216.
11. Krajnc, M.; Levec, J. The role of catalyst in supercritical water oxidation of acetic acid. Appl. Catal. B: Environ. 1997, 13, 93.
12. 2. M.S. Thesis, The University of Texas at Austin, Austin, TX, 1992.
13. Frisch, M. A. Catalyzed Supercritical Water Oxidation of Acetic Acid: Kinetics and Anatase Transformation. Ph.D. Dissertation, The University of Texas at Austin, Austin, TX, 1995.
14. Chang, K.; Li, L.; Gloyna, E. F. Supercritical water oxidation of acetic acid by potassium permanganate. J. Hazard. Mater. 1993, 33, 51.
15. Lee, D. S. Heterogeneous oxidation kinetics of acetic acid in supercritical water. Environ. Sci. Technol. 1996, 30, 3487.
16. Krajnc, M.; Levec, J. Catalytic oxidation of toxic organics in supercritical water. Appl. Catal. B: Environ. 1994, 3, L101.
17. 2 in supercritical water. Ind. Eng. Chem. Res. 1999, 38, 3793.
18. Fogler, H. S. Elements of Chemical Reaction Engineering, 3rd ed.; Prentice Hall PTR: Upper Saddle River, NJ, 1999.
19. Satterfield, C. N. Heterogeneous Catalysis in Industrial Practice, 2nd ed.; McGraw-Hill: New York, 1991.