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The triplet-triplet absorption of TPM was not reported, however, that of diphenylmethane appeared in the visible region as reported in: Fujiwara, M.; Yamasaki, A. J. Chem. Soc., Faraday Trans. 1998, 94, 2525. The triplet state of TPM would also appear in the visible region by analogy with diphenylmethane, however, significant absorption was not observed in the transient absorption spectra. We concluded that the triplet state formation is negligible. In addition, if the triplet state absorbed the second photon, TPM would be ionized, however, a cation radical was not observed.
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TPM cation radical has a maximum absorption at around 480 and 700 nm in dichloromethane. Akaba, R.; Kamata, M.; Itoh, H.; Nakao, A.; Goto, S.; Saito, K.; Negishi, A.; Sakuragi, H.; Tokumara, K. Tetrahedron Lett. 1992, 33, 7011.
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85037457970
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Assuming that the collisional frequency is 5 x 107 Torr″1 s″1. The correlation between the reciprocal of the absorbance of TPM radical (310 nm) and nitrogen gas pressure shows the Stern-Volmer constant of 3.1 x IQ″3 Ton-1
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Assuming that the collisional frequency is 5 x 107 Torr″1 s″1. The correlation between the reciprocal of the absorbance of TPM radical (310 nm) and nitrogen gas pressure shows the Stern-Volmer constant of 3.1 x IQ″3 Ton-1.
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26
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0001026661
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85037480351
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The vibrational energies and the 99 eigenvalues of vibration which was required for RRKM calculation were obtained by Gaussian 94 (HF, 6-31 G(d, p)). The scaling factor of 0.91 was used for adjusting the calculated data to the experimental data. The vibrational frequencies of the activated complex were assumed to be reduce'd to 90% of those in the ground state. The collisional deactivation of hot molecule before the second and third photon absorption was not consisted in the calculation. The obtained values are then the maximum values. Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Gill, P. M. W.; Johnson, B. G.; Robb, M. A.; Cheeseman, J. R.; Keith, T.; Petersson, G. A.; Montgomery, J. A.; Raghavachari, K.; Al-Laham, M. A.; Zakrzewski, V. G.; Ortiz, J. V.; Foresman, J. B.; Cioslowski, J.; Stefanov. B. B.; Nanayakkara, A.; Challacombe, M.; Peng, C. Y.; Ayala, P. Y.; Chen, W.; Wong, M. W.; Andres, J. L.; Replogle, E. S.; Gomperts, R.; Martin, R. L.; Fox, D. J.; Binkley, J. S.; Defrees, D. J.; Baker, J.; Stewart, J. P.; Head-Gordon, M.; Gonzalez, C.; Pople, J. A. Gaussian 94, SGI-G94RevE. I ; Gaussian, Inc.: Pittsburgh, PA, 1995.
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Pople, J.A.35
more..
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33
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0012231020
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Assuming the homolytic bond dissociation energy of benzylic C-H bond of TPM is 339 kJ mor1. Zhang, X.; Bordwell, F. G. J. Am. Chem. Soc. 1992, 114, 9787.
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34
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85037489542
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The time profile at 230 nm has an instrumental response limited rise. It is reasonable to assume the instantaneous hot TPM formation due to the fast internal conversion
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The time profile at 230 nm has an instrumental response limited rise. It is reasonable to assume the instantaneous hot TPM formation due to the fast internal conversion.
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36
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0000082323
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Nakashima, N.; Nakamura, S.; Sakabe, S.; Schilinger, H.; Hamanaka, Y.; Yamanaka, C.; Kusaba, M.; Ishihara, N.; Izawa, Y. J. Phys. Chem. A 1999, 103, 3910.
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37
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0343589103
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Asian-Pacific Forum on Science and Technology, Kanazawa Japan, Abstract
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Biphenylene dimer was obtained by two-photon process via hot biphenylene. A preliminary result was reported in: Yatsuhashi, T.; Akiho, T.; Shimizu, S.; Nakashima, N. Abstracts of Papers, Asian-Pacific Forum on Science and Technology, Kanazawa Japan, 1998; Abstract, p 58.
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Abstracts of Papers
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Yatsuhashi, T.1
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Nakashima, N.4
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