NMR cross-polarization when TIS>T1ρ; examples from silica Gel and calcium silicate hydrates

Journal of Physical Chemistry B

Volumn 104, Issue 44, 2000, Pages 10162-10167

  Klur, I ^a,e   Jacquinot, J F ^b   Brunet, F ^c   Charpentier, T ^d   Virlet, J ^a,c   Schneider, C ^e   Tekely, P ^a  

^a Service de Chimie Moléculaire   (France)

^b SERVICE DE PHYSIQUE DE L ETAT CONDENSÉ   (France)

^c UNIVERSITÉ DE LORRAINE   (France)

^d CEA SACLAY   (France)

^e Rhodia Recherches   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CALCIUM COMPOUNDS; HYDRATES; MAGNETIC RELAXATION; MAGNETIZATION; POLARIZATION; SILICA GEL;

CALCIUM SILICATE HYDRATES;

NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

EID: 0034323236     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp001342u     Document Type: Article

References (34)

1. Pines, A.; Gibby, M. G.; Waugh, J. S. J. Chem. Phys. 1973, 59, 369.
2. McArthur, D.; Hahn, E. L.; Waldstaet, R. E. Phys. Rev. 1969, 188, 609.
3. Mehring, M. High-Resolution NMR in Solids, NMR Basic Principles and Progress; Springer: New York; 1983.
4. Michel, D.; Engelke, F. Solid State NMR III, Organic Matter, NMR Basic Principles and Progress; Springer: New York, 1994; pp 32, 69.
5. Schaefer, J.; Stejskal, E. O.; Buchdahl, R. Macromolecules 1977, 10, 384.
6. Klein Douwel C. H.; Maas W. E. J. R,; Veeman V. S.; Weremeus Buning G. H.; Vankan J. M. J., Macromolecules 1990, 23, 406;
7. Maas, W. E. J. R.; Van der Heijden, W. A. C.; Veeman, W. S.; Vankan, J. M.; Werumeus Buring, G. H. J. Chem. Phys. 1991, 95, 4698;
8. Veeman, W. S.; Maas, W. E. J. R., Solid State NMR III, Organic Matter, NMR Basic Principles and Progress; Springer: New York, 1994; pp 32, 127.
9. Monti, G. A.; Harris, R. K. Magn. Reson. Chem. 1998, 36, 892;
10. Ando, S.; Harris, R. K.; Monti, G. A.; Reinsberg, S. A. J. Magn. Reson. 1999, 141, 91.
11. Mortuza, M. G.; Dupree, R.; Kohn, S. C. Appl. Magn. Reson. 1993, 4, 89.
12. Lipmaa, E.; Måai, M.; Samoson A.; Engelhardt, G.; Grimmer, A. R. J. Am. Chem. Soc. 1980, 102, 4889.
13. Klur, I. Thesis, Paris VI, 1996.
14. Klur, I.; Pollet, B.; Virlet, J.; Nonat, A. Nuclear Magnetic Resonance Spectroscopy of Cement-Based Materials; Colombet, P., Grimmer, A. R., Zanni, H., Sozzani, P., Eds.; Springer-Verlag: Berlin, 1998; p 119.
15. UP for λ = 1).
16. This expression is more condensed but strictly equal to that of Mehring (ref 3).
17. IS, whatever the real situation.
18. Tekely, P.; Gérardy, V.; Palmas, P.; Canet, D.; Retoumard, A. Solid State NMR 1995, 4, 361.
19. This may be questioned if there are slow motions, in which case the spectral density functions are expected to be different in the presence of one or two RF fields at the Hartmann-Hahn condition.
20. Taylor, H. F. W. J. Am. Ceram. Soc. 1986, 6, 69.
21. Taylor, H. F. W. Cement Chemistry, 2nd ed.; Thomas Telford Publishing: London; 1997.
22. Hamid, S. A. Zeitschrift für Kristallographie 1981, 154, 189.
23. Nonat, A. Mater. Struct. 1994, 168, 27.
24. Nonat, A.; Lecoq, X. Nuclear Magnetic Resonance Spectroscopy of Cement-Based Materials; Colombet, P., Grimmer, A. R., Zanni, H., Sozzani, P., Eds.; Springer-Verlag: Berlin, 1998; p 197.
25. Cong, X.; Kirkpatrick, R. J. Adv. Cem. Res. 1995, 7, 103.
26. Gauffinet, S.; Knot, E.; Lesniewska, E.; Nonat, A. C. R. Acad. Sc. Paris, Sciences de la Terre et des planètes 1998, 327, 231.
27. A. Nonat, private communication.
28. Leyden, D. E.; Collins, W. T.; Silylated Surfaces; Gordon and Breach Science Publishers: New York; 1980.
29. Maciel, G. E. Encyclopedia of Nuclear Magnetic Resonance; Grant, D. M., Harris, R. K., Eds.; John Wiley and Sons: Chichester, U.K., 1996; p 4370.
30. Maciel, G. E.; Sindorf, D. W. J. Am. Chem. Soc. 1980, 102, 7607.
31. Chuang, I. S.; Kinney, D. R.; Maciel, G. E. J. Am. Chem. Chem. 1993, 115, 8695.
32. Chuang, I. S.; Maciel, G. E. J. Am. Chem. Chem. 1996, 118, 401.
33. Wind, R. A.; Maciel, G.; Botto, R. E. Adv. Chem. Ser. 1993, 229, 3.
34. Snape, C. E.; Axelson, D. E.; Botto, R. E.; Delpuech, J. J.; Tekely, P.; Gerstein, B. C.; Pruski, M.; Maciel, G. E.; Wilson M. A. Fuel 1989, 68, 547-560.