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33645896944
-
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note
-
Instead of using a glovebox, test tubes kept under nitrogen or argon were used for the Quartz procedure. The amount of moisture could then not be measured, but since films prepared in test tubes under slightly different conditions (temperature, reaction time) yielded similar characteristics, this was taken as an indication that enough moisture was present. The method of using test tubes instead of beakers is convenient. Furthermore, the wafers are kept separated from each other and contact that might damage the surfaces is avoided.
-
-
-
-
19
-
-
33645916945
-
-
Generally, the reaction was completed within 30 min as judged by ellipsometry measurements
-
Generally, the reaction was completed within 30 min as judged by ellipsometry measurements.
-
-
-
-
20
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0001419213
-
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For a similar preparation, see: Palacin, S.; Ruaudel-Teixier, A.; Barraud, A. J. Phys. Chem. 1986, 90, 6237.
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a) Dewar, M. J. S.; Zoebisch, E. G.; Healy, E. F. J. Am. Chem. Soc. 1985, 707,3902.
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26
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-
33645913456
-
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The calculation routine SHADOW was programmed by Johan Trygg and Anders Berglund, Department of Chemistry, Chemometrics Group, Umeå University
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The calculation routine SHADOW was programmed by Johan Trygg and Anders Berglund, Department of Chemistry, Chemometrics Group, Umeå University.
-
-
-
-
28
-
-
33645947247
-
-
note
-
Since typically is integrated over more than one absorption band, it does not describe the dipole strength or oscillator strength of a specific transition (which is obtained by integration only over the specific absorption band in energy units).
-
-
-
-
30
-
-
85088005884
-
-
4+ 670 nm
-
4+ 670 nm.
-
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31
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0001224303
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32
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33645925237
-
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If existing, out-of-plane charge-transfer transitions involving the Cu ion are assumed to make only small contributions to the total absorption envelope
-
If existing, out-of-plane charge-transfer transitions involving the Cu ion are assumed to make only small contributions to the total absorption envelope.
-
-
-
-
33
-
-
33645919224
-
-
note
-
With the suggested bonding of the spacer molecule to the substrate, the chromophore plane cannot become coplanar (0°) with the substrate surface; the MO calculations show an angle of 22° in the 'most parallel' orientation.
-
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34
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0026493748
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36
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33645942634
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A thickness of 10 A is reported in ref 5
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A thickness of 10 A is reported in ref 5.
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