Intramolecular coupling of two cyclopentadienyl ring systems of zirconium-unprecedented formation of a dihydride and preparation of the [{(MeC5H4)Zr}5(μ5-N)(μ 3-NH)4(μ-NH2)4] cluster in a two-phase system

Organometallics

Volumn 19, Issue 23, 2000, Pages 4675-4677

  Bai, Guangcai ^a   Müller, Peter ^a   Roesky, Herbert W ^a   Usón, Isabel ^a  

^a UNIVERSITY OF GÖTTINGEN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

AMMONIA; CATALYSTS; HYDRIDES; SYNTHESIS (CHEMICAL); ZIRCONIUM COMPOUNDS;

ANSA-ZIRCONOCENE DIHYDRIDE; CYCLOPENTADIENYL ZIRCONIUM RING; INTRAMOLECULAR COUPLING;

ORGANOMETALLICS;

EID: 0034321013     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0004500     Document Type: Article

References (5)

1. (a) Couturier, S.; Tainturier, G.; Gautheron, B. J. Organomet. Chem: 1980, 195, 291.
2. (b) Choukroun, R.; Basso-Bert, M.; Gervais, D. J. Chem. Soc., Chem. Commun. 1986, 1317.
3. (c) Larsonneur, A.-M.; Choukroun, R. Organometallics 1993, 12, 3216.
4. (d) Carr, A. G.; Dawson, D. M.; Thomton-Pett, M.; Bochmann, M. Organometallics 1999, 18, 2933.
5. (e) Corker, J.; Lefebvre, F.; Lécuyer, C.; Dufaud, V.; Quignard, F.; Choplin, A.; Evans, J.; Basset, J.-M. Science 1996, 271, 966.