Crossed beam reaction of cyano radicals with hydrocarbon molecules. III. Chemical dynamics of vinylcyanide (C2H3CN;X 1A′) formation from reaction of CN(X2∑+) with ethylene, C2H4(X 1Ag)

Journal of Chemical Physics

Volumn 113, Issue 19, 2000, Pages 8643-8655

  Balucani, N ^a,c   Asvany, O ^a,d   Chang, A H H ^a   Lin, S H ^a   Lee, Y T ^a   Kaiser, R I ^a,d,e   Osamura, Y ^b  

^a INSTITUTE OF ATOMIC AND MOLECULAR SCIENCES   (Taiwan)

^b RIKKYO UNIVERSITY   (Japan)

^c UNIVERSITY OF PERUGIA   (Italy)

^d CHEMNITZ UNIVERSITY OF TECHNOLOGY   (Germany)

^e NATIONAL TAIWAN UNIVERSITY   (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRON ENERGY LEVELS; ELECTRONIC STRUCTURE; ETHYLENE; MOLECULAR BEAMS; MOLECULAR DYNAMICS;

COLLISION ENERGIES; CYANO RADICALS; VINYLCYANIDES;

CYANIDES;

EID: 0034319826     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.1289529     Document Type: Article

References (34)

1. For recent reviews see: P. Casavecchia, Rep. Prog. Phys. 63, 355 (2000);
2. P. Casavecchia, N. Balucani, and G. G. Volpi, Annu. Rev. Phys. Chem. 50, 347 (1999).
3. J. C. Whitehead, Rep. Prog. Phys. 59, 993 (1996);
4. K. Liu, R. G. Mac-Donald, and A. F. Wagner, Int. Rev. Phys. Chem. 9, 187 (1990).
5. R. I. Kaiser, J. Ting, L. C. L. Huang, N. Balucani, O. Asvany, Y. T. Lee, H. Chan, D. Stranges, and D. Gee, Rev. Sci. Instrum. 70, 4185 (1999).
6. L. C. L. Huang, Y. T. Lee, and R. I. Kaiser, J. Chem. Phys. 110, 7119 (1999).
7. L. C. L. Huang, N. Balucani, Y. T. Lee, R. I. Kaiser, and Y. Osamura, J. Chem. Phys. 111, 2857 (1999).
8. N. Balucani, O. Asvany, A. H. H. Chang, S. H. Lin, Y. T. Lee, R. I. Kaiser, H. F. Bettinger, P. v. R. Schleyer, and H. F. Schaefer III, J. Chem. Phys. 111, 7457 (1999).
9. N. Balucani, O. Asvany, A. H. H. Chang, S. H. Lin, Y. T. Lee, R. I. Kaiser, H. F. Bettinger, P. v. R. Schleyer, and H. F. Schaefer III, J. Chem. Phys. 111, 7472 (1999).
10. G. Scoles, Atomic and Molecular Beam Methods (New York University Press, New York, 1988), Vol. 1.
11. D. W. Clarke and J. P. Ferris, "Origins of life and evolution of the biosphere 27," 1997, p. 225;
12. ESA Special Publication SP-338, 1992, Symposium on Titan.
13. F. Raulin et al., Adv. Space Res. 22, 353 (1998).
14. I. W. M. Smith, I. R. Sims, and B. R. Rowe, Chem. Eur. J. 3, 1925 (1997).
15. Molecules in Interstellar Environments, edited by E. F. van Dishoeck (Kluwer, Dordrecht, 1997).
16. G. N. Robinson, R. E. Continetti, and Y. T. Lee, J. Chem. Phys. 92, 275 (1990);
17. J. M. Farrar and Y. T. Lee, ibid. 65, 1414 (1976);
18. J. M. Parson, K. Shobatake, Y. T. Lee, and S. A. Rice, Faraday Discuss. Chem. Soc. 55, 344 (1973).
19. Y. T. Lee, J. D. McDonald, P. R. LeBreton, and D. R. Herschbach, Rev. Sci. Instrum. 40, 1402 (1969);
20. R. I. Kaiser et al., J. Chem. Phys. (in press).
21. G. O. Brink, Rev. Sci. Instrum. 37, 857 (1966);
22. N. R. Daly, ibid. 31, 264 (1960).
23. A. D. Becke, J. Chem. Phys. 97, 9173 (1992).
24. C. Lee, W. Yang, and R. G. Parr, Phys. Rev. B 37, 785 (1988).
25. R. Krishnan, M. Frisch, and J. A. Pople, J. Chem. Phys. 72, 4244 (1988).
26. M. J. Frisch, G. W. Trucks, H. B. Schlegel et al., GAUSSIAN 98, Revision D.4, Gaussian, Inc., Pittsburgh, PA, 1998.
27. G. D. Purvis and R. J. Bartlett, J. Chem. Phys. 76, 1910 (1982).
28. H. Eyring, S. H. Lin, and S. M. Lin, Basis Chemical Kinetics (Wiley, New York, 1980).
29. R. I. Kaiser, C. Ochsenfeld, M. Head-Gordon, and Y. T. Lee, Science 274, 1508 (1996).
30. NIST database http://webbook.nist.gov/.
31. W. B. Miller, S. A. Safron, and D. R. Herschbach, Faraday Discuss. Chem. Soc. 44, 108 (1967).
32. K. Bolton, H. B. Schlegel, W. L. Hase, and K. Song, PCCP 1, 999 (1999).
33. P. Schilke et al., Astrophys. J., Suppl. Ser. 108, 301 (1997).
34. A. Nummelin and P. Bergman, Astron. Astrophys. 341, L59 (1999).