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Volumn 104, Issue 47, 2000, Pages 10964-10968

Carbon monoxide adsorption on selected gold clusters: Highly size-dependent activity and saturation compositions

Author keywords

[No Author keywords available]

Indexed keywords

CATALYST SELECTIVITY; CATALYSTS; GAS ADSORPTION; GOLD; PARTIAL PRESSURE; PRESSURE EFFECTS; SATURATION (MATERIALS COMPOSITION);

EID: 0034318472     PISSN: 10895647     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp002889b     Document Type: Article
Times cited : (134)

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    • note
    • The lower activity of odd-electron clusters may seem counter-intuitive. However, as an anonymous reviewer points out, "As a two-electron donor, CO will have a repulsive interaction with the singly occupied HOMO for even-N clusters. Thus the question is the relative energies of the LUMOs for the even and odd clusters."
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