Odor significance of undesirable degradation compounds in heated triolein and trilinolein

JAOCS, Journal of the American Oil Chemists' Society

Volumn 77, Issue 12, 2000, Pages 1303-1314

  Neff, W E ^a,c   Warner, K ^a   Byrdwell, W C ^b  

^a NATIONAL CENTER FOR AGRICULTURAL UTILIZATION RESEARCH   (United States)

^b FLORIDA ATLANTIC UNIVERSITY   (United States)

^c NONE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DEGRADATION; GAS CHROMATOGRAPHY; MASS SPECTROMETRY; ODOR CONTROL; VOLATILE ORGANIC COMPOUNDS;

OLEIC ACID;

VEGETABLE OILS;

EID: 0034317833     PISSN: 0003021X     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11746-000-0205-3     Document Type: Article

References (32)

1. Warner, K., and T.L. Mounts, Frying Stability of Soybean and Canola Oils with Modified Fatty Acid Compositions, J. Am. Oil Chem. Soc. 70:983-988 (1993).
2. Warner, K., P. Orr, L. Parrott, and M. Glynn, Effects of Frying Oil Composition on Potato Chip Stability, Ibid 71:1117-1121 (1994).
3. Warner, K., Property Enhanced Oils, in Proceedings Australian Oilseed Federation Oilseed Forum, 1996, pp. 1-8.
4. Warner, K., P. Orr, and P. Glynn, Effect of Fatty Acid Composition of Oils on Flavor and Stability of Fried Foods, J. Am. Oil Chem. Soc. 74:347-356 (1997).
5. Warner, K., and S. Knowlton, Frying Quality and Oxidative Stability of High-Oleic Corn Oils, Ibid. 74:1317-1322 (1997).
6. Getz, C., Chemical Changes of Oils and Fats at Elevated Temperatures, in Proceedings of the 21st World Congress of the International Society for Fat Research (ISF), The Hague, P J Barnes and Associates, Bridgwater, England, 1995, pp. 577-582.
7. Warner, K., Chemistry of Frying Fats, in Food: Chemistry, Nutrition, and Biotechnology, edited by C.C. Akoh and D.B. Min, Marcel Dekker, New York, 1998, pp. 167-180.
8. Frankel, E.N., Frying Fats, in Lipid Oxidation, The Oily Press, Dundee, Scotland, 1998, pp. 227-248.
9. Chang, S.S., R.J. Peterson, and C.-T. Ho, Chemical Reactions Involved in the Deep-Fat Frying of Foods, J. Am. Oil Chem. Soc. 55:718-727 (1978).
10. Paulose, M.M, and S.S. Chang, Chemical Reactions Involved in the Deep-Fat Frying of Foods: VIII. Characterization of Nonvolatile Decomposition Products of Triolein, Ibid. 55:375-380 (1978).
11. Gardner, D.R., R.A. Sanders, D.E. Henry, D.H. Tallmadge, and H.W. Wharton, Characterization of Used Frying Oils. Part 1: Isolation and Identification of Compound Classes, Ibid. 69:499-508 (1992).
12. Hansen, S.L., M.R Myers, and W.E. Artz, Nonvolatile Components Produced in Triolein During Deep-Fat Frying, Ibid. 71:1239-1243 (1994).
13. Dobson, G., W.W. Christie, and M.C. Dobarganes, Changes in Molecular Species of Triacylglycerols During Frying, Fats and Oils, Grasas Aceites 47:34-37 (1996).
14. Artz, W.F., S.L. Hansen, and M.R. Myers, Heated Fat-Based Oil Substitutes, Oleic and Linoleic Acid-Esterified Propoxylated Glycerol, J. Am. Oil Chem. Soc. 74:367-374 (1997).
15. Hansen, S.L., W.J. Kruegar, L.B. Dunn, Jr., and W.E. Artz, Nuclear Magnetic Resonance and Gas Chromatography/Mass Spectroscopy Analysis of the Nonvolatile Components Produced During Heating ot Oleic Acid Esterified Propoxylated Glycerol, a Fat Substitute Model Compound, and Trioleylglycerol, J. Agric. Food Chem. 45:4730-4739 (1997).
16. Byrdwell, W.C., and W.E. Neff, Non-volatile Products of Triolein Produced at Frying Temperatures Characterized Using Liquid Chromatography with Online Mass Spectrometric Detection, J. Chromatogr. A 852:417-432 (1999).
17. Neff, W.E., and W.C. Byrdwell, Characterization of Model Triacylglycerol (triolein, trilinolein and trilinolenin) Autoxidation Products via High-Performance Liquid Chromatography Coupled with Atmospheric Pressure Chemical Ionization Mass Spectrometry, Ibid. 818:169-186 (1998).
18. Official Methods and Recommended Practices of the American Oil Chemists' Society, 4th ed., American Oil Chemists' Society, Champaign, 1989, Method Cd 20-91.
19. Warner, K., Flavors and Sensory Evaluation, in Bailey's Industrial Oil and Fat Products, 5th edn., Vol. 1, Edible Oil and Fat Products, General Applications, edited by Y.H. Hui, John Wiley & Sons, Inc., New York, 1996, pp. 105-143.
20. Frankel, E.N., Methods to Determine Extent of Oxidation, in Lipid Oxidation, The Oily Press, Dundee, Scotland, 1998, pp. 79-98.
21. Frankel, E.N., Chemistry of Autoxidation: Mechanism, Products and Flavor Significance, in Flavor Chemistry of Fats and Oils, edited by D.B. Min and T.H. Smouse, American Oil Chemists' Society, Champaign, 1985, pp.1-37.
22. Grosch, W., Reactions of Hydroperoxides - Products of Low Molecular Weight, in Autoxidation of Unsaturated Lipids, edited by H.W.-S. Chan, Academic Press, London, 1987, pp. 95-139.
23. Frankel, E.N., Review: Recent Advances in Lipid Oxidation, J. Sci. Food Agric. 54:495-511 (1991).
24. Przbylski, R., and N.A.M. Eskin, Methods to Measure Volatile Compounds and The Flavor Significance of Volatile Compounds, in Methods to Assess Quality and Stability of Oils and Fat-Containing Foods, edited by K. Warner and N.A.M. Eskin, AOCS Press, Champaign, 1995, pp. 107-145.
25. Frankel, E.N., Hydroperoxide Decomposition, in Lipid Oxidation, The Oily Press, Dundee, Scotland, 1998, pp. 55-77.
26. Mahungu, S.M., S.L. Hansen, and W.E. Artz, Quantitation of Volatile Compounds in Heated Triolein by Static Headspace Capillary Gas Chromatography/Infrared Spectroscopy - Mass Spectrometry, J. Am. Oil Chem. Soc. 71:453-455 (1994).
27. Mahungu, S.M., S.L. Hanson, and W.E. Artz, Identification and Quantitation of Volatile Compounds in Two Heated Model Compounds, Trilinolein and Linoleic Acid Esterified Propoxylated Glycerol, J. Agric. Food Chem. 47:690-694 (1999).
28. Debbrecht, F.J., Quantitative Analysis, in Modern Practice of Gas Chromatography, edited by R.L. Grob, John Wiley & Sons, New York. 1997, pp. 166-210.
29. Snyder, J.M., E.N. Frankel, E. Selke, and K. Warner, Comparison of Gas Chromatographic Methods for Volatile Lipid Oxidation Compounds in Soybean Oil, J. Am. Oil Chem. Soc. 65:1617-1620 (1988).
30. Gardner, H.W., and E. Selke, Volatiles from Thermal Decomposition of Isomeric Methyl (12S,13S)-(E)-12, 13-Epoxy-9-hydroperoxy-10-octadecenoates, Lipids 19:375-380 (1984).
31. Gardner, H.W., Oxygen Radical Chemistry of Polyunsaturated Fatty Acids, Free Radical Biol. Med. 7:65-86 (1989).
32. Neff, W.E., and W.C. Byrdwell, Triacylglycerol Analysis by High Performance Liquid Chromatography-Atmospheric Pressure Chemical Ionization Mass Spectrometry: Crepix alpina and Vernonia galamensis Seed Oils, J. Liq. Chromatogr. 18:4165-4181 (1995).