All-carbon [60]fullerene oligomers of pearl-necklace type

Fullerene Science and Technology

Volumn 8, Issue 6, 2000, Pages 545-559

  Dragoe, N ^c   Nakahara, K ^a   Shimotani, H ^a   Xiao, L ^a   Tanibayashi, S ^a   Higuchi, T ^b   Kitazawa, K ^c  

^a UNIVERSITY OF TOKYO   (Japan)

^b JEOL LTD   (Japan)

^c NONE

Author keywords

[No Author keywords available]

Indexed keywords

ATOMS; DERIVATIVES; FOURIER TRANSFORM INFRARED SPECTROSCOPY; GEL PERMEATION CHROMATOGRAPHY; MASS SPECTROMETRY; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OLIGOMERS; SCANNING TUNNELING MICROSCOPY; ULTRAVIOLET SPECTROSCOPY;

METHANO FULLERENE DERIVATIVES; THERMOLYSIS;

FULLERENES;

EID: 0034317802     PISSN: 1064122X     EISSN: None     Source Type: Journal    
DOI: 10.1080/10641220009351433     Document Type: Article

References (28)

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17. TG-MS was performed in inert atmosphere (Ne flow) with a Seiko TG/DTA6300 coupled with a GC HP5890 through a stainless steel coupling line of 0.25 mm diameter, 5 m length, kept at 300°C. The MS was Jeol AutoMass System II measuring every second in the range 10-900 amu. GC-MS was measured with a Double Shot pyroliser FrontierLab 2010D coupled with an AutoMass System II measuring every second in the range 8 to 350 amu.
18. Although no indices of cyclopropane decomposition has been found, in agreement with a reaction mechanism described in Scheme 1, the relative large amount of C60 in the reaction product (10 to 30 %) suggests that a cyclopropane decomposition reaction may occur either from the starting compounds of from the products.
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