Evidence for intramolecular permutation (pseudorotation) at the central antimony atom and strong equatophilicity of an iron and a ruthenium ligand in pentacoordinate hypervalent antimony compound

Organometallics

Volumn 19, Issue 24, 2000, Pages 5122-5133

  Toyota, Koichiro ^a   Wakisaka, Yukiya ^a   Yamamoto, Yohsuke ^a   Akiba, Kin ya ^a  

^a HIROSHIMA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ANTIMONY COMPOUNDS; ATOMS; CHEMICAL BONDS; IRON; IRRADIATION; ISOMERIZATION; MOLECULAR DYNAMICS; NEGATIVE IONS; RUTHENIUM; STEREOCHEMISTRY; SYNTHESIS (CHEMICAL); X RAY CRYSTALLOGRAPHY;

EQUATOPHILICITY; INTRAMOLECULAR PERMUTATION; PENTACOORDINATE HYPERVALENT ANTIMONY COMPOUNDS; STIBORANIDE ANION; TRIPHENYLPHOSPHINE;

ORGANOMETALLICS;

EID: 0034314577     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om000790l     Document Type: Article

References (4)

1. (a) Malisch, W.; Panster, P. Angew. Chem., Int. Ed. Engl. 1974, 13, 670.
2. (b) Malisch, W.; Panster, P. Chem. Ber. 1975, 108, 700.
3. (c) Malisch, W.; Kaul. H.-A.; Gross, E.; Thewalt, U. Angew. Chem., Int. Ed. Engl. 1982, 21, 549.
4. Angew. Chem. Supp. 1982, 1281.