Bis(triflate ester)s having an additional functional group: Initiators for the preparation of α,ω,kentro-telechelic poly(THF)s

Macromolecules

Volumn 33, Issue 23, 2000, Pages 8898-8903

  Oike, Hideaki ^a   Kobayashi, Shinji ^a   Tezuka, Yasuyuki ^a   Goethals, Eric J ^b  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^b GHENT UNIVERSITY   (Belgium)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOLS; INITIATORS (CHEMICAL); MACROMOLECULES; MOLECULAR STRUCTURE; POLYMERIZATION; SYNTHESIS (CHEMICAL);

BISTRIFLATE ESTERS;

POLYESTERS;

EID: 0034314388     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma001018x     Document Type: Article

References (19)

1. An "α,w,kentro-telechelics" refers to a novel telechelic (thus, end-reactive) polymer precursor, possessing an additional functional grous at the center ("kentro in Greek") position of the chain. We propose the term "α,w,kentro-telechelics", since the usage of the Greek "kentro" is apparently consistent with the Greek-based term "telechelics". This class of telechelics has previously been reported, without referring to the terminology. See: Deffieux, A.; Schappacher, M. Macromolecules 1995, 28, 2629-2636.
2. Webster, O. W. Science 1991, 251, 887-893.
3. Tezuka, Y. Telechelic Oligomers (with cyclic onium salt groups). Polymeric Materials Encyclopedia; Salamone, J. C., Ed.; CRC Press: Boca Raton, FL, 1996; Vol. 11, pp 8263-8268.
4. Van Caeter, P.; Goethals, E. J. Trends Polym. Sci. 1995, 3, 227-233.
5. Oike, H.; Yaguchi, T.; Tezuka, Y. Macromol. Chem. Phys. 1999, 200, 768-773.
6. Dubreuil, M. F.; Goethals, E. J. Macromol. Chem. Phys. 1997, 198, 3077-3087.
7. Dubreuil, M. F.; Farcy, N. G.; Goethals, E. J. Macromol. Rapid Commun. 1999, 20, 383-386.
8. Oike, H.; Yoshioka, Y.; Kobayashi, S.; Nakashima, M.; Tezuka, Y.; Goethals, E. J. Macromol. Rapid Commun., in press.
9. Tezuka, Y.; Goethals, E. J. Eur. Polym. J. 1982, 18, 991-998.
10. In case of the polymerization of in situ prepared allyl triflate, the formation of a small portion, i.e., less than 5%, of diallyl ether was reported. See ref 6.
11. Tezuka, Y. Prog. Polym. Sci. 1992, 17, 471-514.
12. Oike, H.; Imamura, H.; Imaizumi, H.; Tezuka, Y. Macromolecules 1999, 32, 4819-4825.
13. Oike, H.; Imamura, H.; Tezuka, Y. Macromolecules 1999, 32, 8666-8670.
14. Oike, H.; Imamura, H.; Tezuka, Y. Macromolecules 1999, 32, 8816-8820.
15. Oike, H.; Imaizumi, H.; Mouri, T.; Yoshioka, Y.; Uchibori, A.; Tezuka, Y. J. Am. Chem. Soc. 2000, 122, 9592-9599.
16. Schloss, J. V.; Hartman, F. C. Bioorg. Chem. 1980, 9, 217-226.
17. Höger, S. Synthesis 1997, 20-22.
18. Mitsunobu, O. Synthesis 1981, 1-28.
19. Burgess, F. J.; Cunliffe, A. V.; Dawkins, J. V.; Richards, D. H. Polymer 1977, 18, 733-740.