Thermogravimetric measurement of hydrogen absorption in alkali-modified carbon materials

Journal of Physical Chemistry B

Volumn 104, Issue 40, 2000, Pages 9460-9467

  Pinkerton, F E ^a   Wicke, B G ^a   Olk, C H ^a   Tibbetts, G G ^a   Meisner, G P ^a   Meyer, M S ^a   Herbst, J F ^a  

^a GENERAL MOTORS CORPORATION   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; CHEMICAL MODIFICATION; GRAPHITE; HIGH TEMPERATURE EFFECTS; HYDROGEN; INTERCALATION COMPOUNDS; ISOTHERMS; LITHIUM; NANOTUBES; POTASSIUM; THERMOGRAVIMETRIC ANALYSIS; WATER;

ALKALI MODIFIED CARBON MATERIALS; LITHIUM CONTAINING CARBON MATERIALS; POTASSIUM INTERCALATED GRAPHITE; PRESSURE COMPOSITION ISOTHERM; THERMOGRAVIMETRIC ANALYZER; THERMOGRAVIMETRIC MEASUREMENT;

GAS ABSORPTION;

EID: 0034299395     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp000957o     Document Type: Article

References (26)

1. Dillon, A. C.; Jones, K. M.; Bekkedahl, T. A.; Kiang, C. H.; Bethune, C. H.; Heben, M. J. Nature 1997, 386, 377.
2. Liu, C.; Fan, Y.-Y.; Liu, M.; Cong, H. T.; Cheng, H. M.; Dresselhaus, M. S. Science 1999, 286, 1127.
3. Fan, Y.-Y.; Liao, B.; Liu, M.; Wei, Y.-L.; Lu, M.-Q.; Cheng, H.-M. Carbon 1999, 37, 1649.
4. Chambers, A.; Park, C.; Baker, R. T. K.; Rodriguez, N. M. J. Phys. Chem. 1998, B102, 4253.
5. Park, C.; Anderson, P. E.; Chambers, A.; Tan, C. D.; Hidalgo, R.; Rodriguez, N. M. J. Phys. Chem. 1999, B103, 10572.
6. Ye, Y.; Ahn, C. C.; Witham, C.; Fultz, B.; Liu, J.; Rinzler, A. G.; Colbert, D.; Smith, K. A.; Smalley, R. E. Appl. Phys. Lett. 1999, 74, 2307.
7. Tibbetts, G. G.; Meisner, G. P.; Olk, C. H. Unpublished results.
8. Chen, P.; Wu, X.; Lin, J.; Tan, K. L. Science 1999, 285, 91.
9. Yang, R. T. Carbon 2000, 38, 623.
10. Zanini, M.; Basu, S.; Fisher, J. E. Carbon 1978, 16, 211.
11. Kiat, J. M.; Boemare, G.; Rieu, B.; Aymes, D. Solid State Commun. 1998, 108, 241.
12. Brauer, G., Ed.; Handbook of Preparative Inorganic Chemistry, 2nd Ed.; Academic Press: New York, 1963; Vol. 1, pp 974-975.
13. 2, we conclude that LiOH is far more likely to be the low-temperature species.
14. Dresselhaus, M. S.; Dresselhaus, G. Adv. Phys. 1981, 30, 139.
15. Wu, G. T.; Wang, C. S.; Zhang, X. B.; Yang, H. S.; Qi, Z. F.; He, P. M.; Li, W. Z. J. Electrochem. Soc. 1999, 146, 1696.
16. Leroux, F.; Méténier, K.; Gautier, S.; Frackowiak, E.; Bonnamy, S.; Béguin, F. J. Power Sources 1999, 81-82, 317.
17. Mordkovich, V. Z.; Baxendale, M.; Yoshimura, S.; Chang, R. P. H. Carbon 1996, 34, 1301.
18. Mordkovich, V. Z.; Baxendale, M.; Chang, R. P. H.; Yoshimura, S. Synth. Met. 1997, 86, 2049.
19. Suzuki, S.; Tomita, M. J. Appl. Phys. 1996, 79, 3739.
20. Eklund, P. C.; Oik, C.; Holler, F. J.; Spolar, J. G.; Arakawa, E. T. J. Mater. Res. 1986, 1, 361.
21. Hooley, J. G. Mater. Sci. Eng. 1977, 31, 17.
22. Zhou, O.; Fleming, R. M.; Murphy, D. W.; Chen, C. H.; Haddon, R. C.; Ramirez, A. P.; Glarum, S. H. Science 1994, 263, 1744.
23. Sublimation temperatures for alkali metal hydroxides (excluding LiOH) are said to be 350-400 °C [Cotton, F. A.; Wilkinson, G. Advanced Inorganic Chemistry, 3rd Ed.; John Wiley and Sons: New York, 1972; pp 191, 196]. Our K-intercalated samples, however, do not lose weight until 600 °C or above, accompanied by deposition of material that we believe to be KOH on the furnace tube. The higher sublimation temperature may reflect binding of the KOH within the carbon structure.
24. Pickering, Trans. Chem. Soc. 1893, 63, 908.
25. Linke, W. F. Solubilities of Inorganic and Metal Organic Compounds; Seidell, Ed.; American Chemical Society: Washington, DC, 1965; Vol. II, pp 276, 1084, 1378.
26. Lagrange, A. P.; Hérold, A. Carbon 1978, 16, 235.