Synthesis and structures of the crystalline heavier alkali metal alkyls: X-ray structures of [K(μ-R){O(Me)But}]∞, [(pmdeta)K(μ-R)K(μ-R)2K(μ-R)K(pmdeta)], and [Cs(μ-R)(tmeda)]∞ (R = CH(SiMe3)2)

Organometallics

Volumn 19, Issue 20, 2000, Pages 4030-4035

  Marco Boesveld, W ^a   Hitchcock, Peter B ^a   Lappert, Michael F ^a   Liu, Dian Sheng ^a   Tian, Shun ^a  

^a UNIVERSITY OF SUSSEX   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

CESIUM COMPOUNDS; CRYSTAL STRUCTURE; CRYSTALLINE MATERIALS; LITHIUM COMPOUNDS; POTASSIUM COMPOUNDS; RUBIDIUM COMPOUNDS; SODIUM COMPOUNDS; SOLUBILITY; SYNTHESIS (CHEMICAL); X RAY CRYSTALLOGRAPHY;

CESIUM AZAALLYL; CRYSTALLINE HEAVIER ALKALI METAL ALKYLS; NEUTRAL LIGAND; X RAY STRUCTURES;

ORGANOMETALLICS;

EID: 0034299198     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0004287     Document Type: Article

References (10)

1. The Second International Conference on the Chemistry of the Alkali and Alkaline Earth Metals, Erlangen, Germany, Sept 1997.
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3. Schade, C.; Schleyer, P. v. R. Adv. Organomet. Chem. 1987, 27, 169.
4. Gregory, K.; Schleyer, P. v. R.; Snaith, R. Adv. Inorg. Chem. 1991, 37,47.
5. Sapse, A. M., Schleyer, P. v. R., Eds. Lithium Chemistry; Wiley: New York, 1994.
6. Snieckus, V. Chem. Rev. 1990, 90, 879.
7. Brandsma, L.; Verkruijsse, H. Preparative Polar Organometallic Chemistry; Springer: Berlin. 1987: Vol. 1.
8. (a) Weiss, E. Angew. Chem., Int. Ed. Engl. 1993, 32, 1501.
9. (b) Smith, J. D. Adv. Organomet. Chem. 1999, 43, 267.
10. Collier, M. R.; Kingston, B. M.; Lappert, M. F.; Truelock, M. M. Brit. Patent 36021, 1969.