Why does the tetrakis(trimethylphosphine)iridium(III) hydridochloride cation adopt the sterically and electronically unfavorable cis geometry?

Organometallics

Volumn 19, Issue 22, 2000, Pages 4608-4612

  Blum, Ofer ^a  

^a WEIZMANN INSTITUTE OF SCIENCE   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

COMPLEXATION; ENTROPY; ISOMERIZATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; QUANTUM THEORY; STRUCTURE (COMPOSITION); THERMODYNAMIC STABILITY;

QUANTUM CHEMICAL CALCULATIONS; STEREOSPECIFIC CATALYSIS; TETRAKISTRIMETHYLPHOSPHINE IRIDIUM;

ORGANOMETALLICS;

EID: 0034295246     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0004848     Document Type: Article

References (3)

1. (a) Fernandez, A. L.; Prock, A.; Giering, W. P. Organometallics 1996, 15, 2784.
2. (b) Wilson, M. R.; Liu, H.; Frock, A.; Giering, W. P. Organometallics 1993, 12, 2044.
3. Atwood, J. D. Inorganic and Organometallic Reaction Mechanisms, 2nd ed.; VCH: New York, 1997.