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Volumn 104, Issue 42, 2000, Pages 9646-9652

Formation of intramolecular three-electron-bonded 2σ/1σ* radical cations upon reduction of dialkylsulfinyl sulfides by H-atoms

Author keywords

[No Author keywords available]

Indexed keywords

HYDROGEN; POSITIVE IONS; REACTION KINETICS; REDUCTION; SULFUR COMPOUNDS;

EID: 0034293939     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp0018706     Document Type: Article
Times cited : (14)

References (42)
  • 3
    • 0002029213 scopus 로고    scopus 로고
    • Page, P. C. B., Ed.; Wiley: New York
    • Glass, R. S. In Sulfur Radical Cations; Page, P. C. B., Ed.; Wiley: New York, 1998; Vol. III.
    • (1998) Sulfur Radical Cations , vol.3
    • Glass, R.S.1
  • 28
  • 34
    • 1542783446 scopus 로고
    • Packer, L., Ed.; Academic Press: Orlando, FL
    • Asmus, K.-D. In Pulse Radiolysis Methodology; Packer, L., Ed.; Academic Press: Orlando, FL, 1990; Vol. 105, p 167.
    • (1990) Pulse Radiolysis Methodology , vol.105 , pp. 167
    • Asmus, K.-D.1
  • 37
    • 85037471478 scopus 로고    scopus 로고
    • note
    • The minimum is accounted for by G = 0.6 of primary H-atoms plus G = 2.8 of secondary H-atoms formed upon conversion of hydrated electron by protons at pH ≈ 3-4. At higher proton concentrations the latter interfere with geminate recombination processes of hydrated electrons which further enhances the yield of scavengeable H-atoms.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.