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Volumn 38, Issue 17, 2000, Pages 3106-3127

Experimental and theoretical investigations of the structure of methylaluminoxane (MAO) cocatalysts for olefin polymerization

Author keywords

[No Author keywords available]

Indexed keywords

ALUMINUM COMPOUNDS; CATALYSTS; CHEMICAL BONDS; INFRARED SPECTROSCOPY; MOLECULAR STRUCTURE; ORGANOMETALLICS; POLYMERIZATION; RAMAN SPECTROSCOPY;

EID: 0034269375     PISSN: 0887624X     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0518(20000901)38:17<3106::AID-POLA120>3.0.CO;2-T     Document Type: Article
Times cited : (103)

References (63)
  • 12
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    • Dissertation, Universität Hamburg, Germany
    • von Thienen, N. Dissertation, Universität Hamburg, Germany, 1996.
    • (1996)
    • Von Thienen, N.1
  • 14
    • 0342292551 scopus 로고    scopus 로고
    • Thesis, Fortschritt-Berichte VDI, Reihe 3, Nr. 627; VDI-Verlag: Düsseldorf, Germany
    • Ott, M. Optimierung der Herstellung von Methylaluminoxan; Thesis, Fortschritt-Berichte VDI, Reihe 3, Nr. 627; VDI-Verlag: Düsseldorf, Germany, 1999.
    • (1999) Optimierung der Herstellung von Methylaluminoxan
    • Ott, M.1
  • 33
    • 0008791644 scopus 로고    scopus 로고
    • Chemistry Department, Vrije Universiteit, De Boelelaan 1083, 1081 HV Amsterdam, The Netherlands
    • ADF 2.3, Scientific Computing and Modeling, Chemistry Department, Vrije Universiteit, De Boelelaan 1083, 1081 HV Amsterdam, The Netherlands.
    • ADF 2.3, Scientific Computing and Modeling
  • 42
    • 0343597553 scopus 로고    scopus 로고
    • note
    • 3 unit of 23.7 and 22.1 kcal/mol, respectively, indicating a similar stability of MAO ladders with variable lengths.
  • 44
    • 0342292563 scopus 로고    scopus 로고
    • note
    • The dimerization energy is -13.2 kcal/mol for the dimer with one bridging Cl and one bridging methyl and only -7.9 (Cl cis) and -8.9 (Cl trans) with two bridging methyls.
  • 53
    • 0343597548 scopus 로고    scopus 로고
    • The variation in activity is comparable to the reproducibility in our polymerization experiments
    • The variation in activity is comparable to the reproducibility in our polymerization experiments.
  • 59
    • 0343162185 scopus 로고    scopus 로고
    • Dissertation, Universität Hamburg
    • 11
    • (2000)
    • Heitmann, B.1
  • 60
    • 0343162183 scopus 로고    scopus 로고
    • note
    • 1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.