A new class of flexible energetic salts, part 6: The structures of the hydrazinium and hydroxylammonium salts of dinitramide

Journal of Chemical Crystallography

Volumn 30, Issue 9, 2000, Pages 599-604

  Gilardi, Richard ^a   Butcher, Ray J ^b  

^a NAVAL RESEARCH LABORATORY   (United States)

^b HOWARD UNIVERSITY   (United States)

Author keywords

Dinitramide structures; Energetic materials; Hydrazinium structures; Hydroxylamine structures

Indexed keywords

EID: 0034257437     PISSN: 10741542     EISSN: None     Source Type: Journal    
DOI: 10.1023/A:1011362427996     Document Type: Article

References (44)

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22. 1/2, where n is the number of reflections and p is the total number of parameters refined.
23. In this paper, as in all others in this series, the dinitramine anions are consistently labelled such that N1 is the central atom. N2 and N3 are labelled such that the N1-N2 and N1-N3 bonds are larger and smaller respectively. The oxygen atoms are labelled so that O2B and O3B are the interior oxygen atoms.
24. This is a measure of the amount by which the nitro group has rotated out of the N2-N1-N3 plane and is calculated by averaging the two torsion angles N-N-N-O for a particular nitro group (values brought below 90° by adding or subtracting 180°).
25. 3 conformations. The O-O distance is the separation of the two closest nitro oxygen atoms. The torsion angle is a pseudo-torsion angle defined between the two closest N-O bonds in the molecule belonging to different nitro groups, e.g., O2B-N2-N3-O3B.
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44. 3.