NiCl2 on γ-alumina as selective adsorbents for acetylene over ethylene

Industrial and Engineering Chemistry Research

Volumn 39, Issue 8, 2000, Pages 3108-3111

  Kodde, Adriaan J ^a   Padin, Joel ^b   Van Der Meer, Peter J ^a   Mittelmeijer Hazeleger, Marjo C ^a   Bliek, Alfred ^a   Yang, Ralph T ^b  

^a UNIVERSITY OF AMSTERDAM   (Netherlands)

^b UNIVERSITY OF MICHIGAN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACETONE; ACETYLENE; ADSORPTION ISOTHERMS; ALUMINA; ETHYLENE; MASS SPECTROMETRY; NICKEL COMPOUNDS; THERMOGRAVIMETRIC ANALYSIS;

NICKEL CHLORIDE; SELECTIVE ADSORBENTS;

ADSORBENTS;

ACETYLENE; ALUMINUM OXIDE; ETHYLENE; NICKEL CHLORIDE;

ADSORPTION; ARTICLE; CHEMICAL ANALYSIS; CHEMICAL BINDING; EQUILIBRIUM CONSTANT; PURIFICATION; SYNTHESIS; THERMAL ANALYSIS;

EID: 0034253718     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie000080f     Document Type: Article

References (14)

1. Yang, R. T.; Foldes, R. New Adsorbents Based on Principles of Chemical Complexation: Monolayer-Dispersed Nickel(II) for Acetylene Separation by π-Complexation. Ind. Eng. Chem. Res. 1996, 35, 1006.
2. Padin, J.; Yang, R. T. Tailoring New Adsorbents Based on π-Complexation: Cation and Substrate Effects on Selective Acetylene Adsorption. Ind. Eng. Chem. Res. 1997, 36, 4224.
3. Dickerson, D., Praxair Inc., personal communication, 1999.
4. Xie, Y. C.; Tang, Y. Q. Spontaneous Monolayer Dispersion of Oxides and Salts onto Surfaces of Supports: Application to Heterogeneous Catalysis. Adv. Catal. 1990, 37, 1.
5. 3 and Other Supported Transition Metal Salts. Sci. Sin. Ser. B (Engl. Ed.) 1984, 27, 445.
6. Yang, R. T.; Kikkinides, E. S. New Sorbents for Olefin/ Paraffin Separations by Adsorption via π-Complexation. AIChE J. 1995, 41 (3), 509.
7. Encyclopaedic dictionary of physics; Thewis, J., Ed.; Pergamon: Oxford, U.K., 1962; Vol. 7, p 171.
8. Ackley, M. W.; Yang, R. T. Diffusion in Ion-Exchanged Clinoptilolites. AIChE J. 1991, 37 (11), 1645.
9. Paniego, A. R.; Pinto, J. M. G. Adsorption of Olefins and Acetylene on a Silica Gel. I Experimental Results. Anal. Quim. 1977, 73 (9-10), 1067.
10. Lewis, W. K.; Gilliland, E. R.; Chertow, B.; Milliken, W. Vapor-Adsorbate Equilibrium II. Acetylene-Ethylene on Activated Carbon and on Silica Gel J. Am. Chem. Soc. 1950, 72, 1157.
11. Rege, S. U.; Padin, J.; Yang, R. T. Olefin/Parafin Separations by Adsorption: π-Complexation vs. Kinetic Separation. AIChE J. 1998, 44 (4), 799.
12. Hopkinson, A. C. Acidity, hydrogen bonding and complex formation. In The chemistry of the carbon-carbon triple bond; Patai, S., Ed.; John Wiley & Sons: Chichester, U.K., 1978.
13. Kaminsky, M. P.; Wilsak, R. A.; Whittaker, R. C. Olefin Purification by Adsorption of Acetylenics and Regeneration of Adsorbent. WO Patent 98/40450, 1998.
14. Eischens, R. P.; Pliskin, W. A. The Infrared Spectra of Adsorbed Molecules. Adv. Catal. 1958, 10, 1.