Photochemistry of group 14 1,1,1-trimethyl-2,2,2-triphenyldimetallanes (Ph3MM′Me3; M, M′ = Si, Ge). Direct detection and characterization of silene and germene reactive intermediates

Organometallics

Volumn 19, Issue 16, 2000, Pages 3232-3241

  Leigh, William J ^a,b   Toltl, Nicholas P ^a,b   Apodaca, Paula ^a,b   Castruita, Madeli ^a,b   Pannell, Keith H ^a,b  

^a MCMASTER UNIVERSITY   (Canada)

^b UNIVERSITY OF TEXAS AT EL PASO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION SPECTROSCOPY; ACETONE; CHLORINE COMPOUNDS; FREE RADICALS; GERMANIUM COMPOUNDS; HYDROCARBONS; METHANOL; PHENOLS; PHOTOLYSIS; RATE CONSTANTS; SILANES;

CHLOROFORM; LASER FLASH PHOTOLYSIS METHOD; TRAPPING PRODUCT; TRIMETHYLTRIPHENYLDIMETALLANES;

ORGANOMETALLICS;

EID: 0034249905     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om000174p     Document Type: Article

References (4)

1. Shizuka, H.; Hiratsuka, H. Res. Chem. Intermed. 1992, 18, 131.
2. Steinmetz, M. G. Chem. Rev. 1995, 95, 1527.
3. Brook, A. G.; Brook, M. A. Adv. Organomet. Chem. 1996, 39, 71.
4. Brook, A. G. In The chemistry of organic silicon compounds; Rappoport, Z., Apeloig, Y., Eds.; John Wiley and Sons: New York, 1998; pp 1233-1310.