Molecular orientation of single and two-armed monodendron semifluorinated chains on 'soft' and 'hard' surfaces studied using NEXAFS

Macromolecules

Volumn 33, Issue 16, 2000, Pages 6068-6077

  Genzer, Jan ^a,b   Sivaniah, Easan ^b   Kramer, Edward J ^b   Wang, Jianguo ^c,h   Xiang, Maoliang ^c   Char, Kookheon ^c,i   Ober, Christopher K ^c   Bubeck, Robert A ^d   Fischer, Daniel A ^e,f   Graupe, Michael ^g   Colorado Jr , Ramon ^g   Shmakova, Olga E ^g   Lee, T Randall ^g  

^a North Carolina State University   (United States)

^b University of California   (United States)

^c Cornell University   (United States)

^d MICHIGAN MOLECULAR INSTITUTE   (United States)

^e BROOKHAVEN NATIONAL LABORATORY   (United States)

^f NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY   (United States)

^g University of Houston   (United States)

^h Corning Incorporated ^*  (United States)

ⁱ Seoul National University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION SPECTROSCOPY; BLOCK COPOLYMERS; INTERFACIAL ENERGY; MOLECULAR ORIENTATION; POLYISOPRENES; POLYSTYRENES; SUBSTRATES; SURFACE STRUCTURE; X RAY SPECTROSCOPY;

NEAR EDGE ABSORPTION FINE STRUCTURE; SEMIFLUORINATED CHAINS; SEMIFLUORINATED MESOGENS; STYRENE ISOPRENE DIBLOCK COPOLYMER; SURFACE TOPOLOGY;

FLUORINE CONTAINING POLYMERS;

EID: 0034246517     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma991710w     Document Type: Article

References (37)

1. Katano, Y.; Tomono, H.; Nakajima, T. Macromolecules 1994, 27, 2342. Hopken, J.; Möller, M. Macromolecules 1992, 25, 1461. Schneider, J.; Erdelen, C.; Ringsdorf, H.; Rabolt, J. T. Macromolecules 1989, 22, 3475. Rabolt, J. F.; Russell, T. P.; Tweig, R. J. Macromolecules 1984, 17, 2786.
2. Katano, Y.; Tomono, H.; Nakajima, T. Macromolecules 1994, 27, 2342. Hopken, J.; Möller, M. Macromolecules 1992, 25, 1461. Schneider, J.; Erdelen, C.; Ringsdorf, H.; Rabolt, J. T. Macromolecules 1989, 22, 3475. Rabolt, J. F.; Russell, T. P.; Tweig, R. J. Macromolecules 1984, 17, 2786.
3. Katano, Y.; Tomono, H.; Nakajima, T. Macromolecules 1994, 27, 2342. Hopken, J.; Möller, M. Macromolecules 1992, 25, 1461. Schneider, J.; Erdelen, C.; Ringsdorf, H.; Rabolt, J. T. Macromolecules 1989, 22, 3475. Rabolt, J. F.; Russell, T. P.; Tweig, R. J. Macromolecules 1984, 17, 2786.
4. Katano, Y.; Tomono, H.; Nakajima, T. Macromolecules 1994, 27, 2342. Hopken, J.; Möller, M. Macromolecules 1992, 25, 1461. Schneider, J.; Erdelen, C.; Ringsdorf, H.; Rabolt, J. T. Macromolecules 1989, 22, 3475. Rabolt, J. F.; Russell, T. P.; Tweig, R. J. Macromolecules 1984, 17, 2786.
5. Schmidt, D. L.; Coburn, C. E,; DeKoven, B. M.; Potter, G. E.; Meyers, G.; F.; Fisher, D. A. Nature 1994, 368, 39.
6. Pittman, A. G. In Fluoropolymers; Wall, L. A., Ed.; Wiley: New York, 1972; Vol. 25, p 419.
7. Hwang, S. S.; Ober, C. K.; Perutz, S.; Iyengar, D.; Schneggenburger, L. A.; Kramer, E. J. Polymer 1995, 36, 1321. Iyengar, D. R.; Perutz, S. M.; Dai, C.-A.; Ober, C. K.; Kramer, E. J. Macromolecules 1996, 29, 1229.
8. Hwang, S. S.; Ober, C. K.; Perutz, S.; Iyengar, D.; Schneggenburger, L. A.; Kramer, E. J. Polymer 1995, 36, 1321. Iyengar, D. R.; Perutz, S. M.; Dai, C.-A.; Ober, C. K.; Kramer, E. J. Macromolecules 1996, 29, 1229.
9. Cai, Y.; Gardner, D.; Caneba, G. T. J. Adhes. Sci. Technol. 1999, 13, 1017. Chen, X.; Gardella, J. A., Jr. Macromolecules 1994, 27, 3363.
10. Cai, Y.; Gardner, D.; Caneba, G. T. J. Adhes. Sci. Technol. 1999, 13, 1017. Chen, X.; Gardella, J. A., Jr. Macromolecules 1994, 27, 3363.
11. Schmidt, D. L.; DeKoven, B. M.; Coburn, C. E.; Potter, G. E.; Meyers, G. F.; Fischer, D. A. Langmuir 1996, 12, 518.
12. Wang, J.; Mao, G.; Ober, C. K.; Kramer, E. J. Macromolecules 1997, 30, 1906.
13. Genzer, J.; Sivaniah, E.; Kramer, E. J.; Wang, J.; Körner, H.; Xiang, M.; Yang, S.; Ober, C. K.; Char, K.; Chaudhury, M. K.; DeKoven, B. M.; Bubeck, R. A.; Fischer, D. A.; Sambasivan, S. In Applications of Synchrotron Radiation Techniques to Materials Science IV; Mini, S. M., Perry, D. L., Stock, S. R., Terminello, L. J., Eds.; Materials Research Society Symposium Proceedings, Vol. 524; Materials Research Society: Pittsburgh, PA 1998; p 365. Genzer, J.; Sivaniah, E.; Kramer, E. J.; Wang, J.; Körner, H.; Xiang, M.; Char, K.; Ober, C. K.; Chaudhury, M. K.; DeKoven, B. M.; Bubeck, R. A.; Sambasivan, S.; Fischer, D. A. Macromolecules 2000, 33, 1882.
14. Genzer, J.; Sivaniah, E.; Kramer, E. J.; Wang, J.; Körner, H.; Xiang, M.; Yang, S.; Ober, C. K.; Char, K.; Chaudhury, M. K.; DeKoven, B. M.; Bubeck, R. A.; Fischer, D. A.; Sambasivan, S. In Applications of Synchrotron Radiation Techniques to Materials Science IV; Mini, S. M., Perry, D. L., Stock, S. R., Terminello, L. J., Eds.; Materials Research Society Symposium Proceedings, Vol. 524; Materials Research Society: Pittsburgh, PA 1998; p 365. Genzer, J.; Sivaniah, E.; Kramer, E. J.; Wang, J.; Körner, H.; Xiang, M.; Char, K.; Ober, C. K.; Chaudhury, M. K.; DeKoven, B. M.; Bubeck, R. A.; Sambasivan, S.; Fischer, D. A. Macromolecules 2000, 33, 1882.
15. (a) Butoi, C. I.; Mackie, N. M.; Barnd, J. L.; Fisher, E. R.; Gamble, L. J.; Castner, D. G. Chem. Mater. 1999, 11, 862.
16. (b) Castner, D, G.; Lewis, K. B., Jr.; Fischer, D. A.; Ratner, B. D.; Gland, J. L. Langmuir 1993, 9, 537.
17. Xiang, M.; Li, X.; Ober, C. K.; Char, K.; Genzer, J.; Sivaniah, E.; Kramer, E. J., in press.
18. 1H NMR characterization. The concentration of polymer for this study was kept at 5-10 mg/mL.
19. Graupe, M.; Koini, T.; Wang, V. Y.; Nassif, G. M.; Colorado, R.; Villazana, R. J.; Dong, H.; Miura, Y. F.; Shmakova, O. E.; Lee, T. R. J. Fluor. Chem. 1999, 93, 107.
20. Colorado, R., Jr.; Lee, T. R.; Genzer, J.; Sivaniah, E.; Kramer, E. J.; Char, K.; Ober, C. K.; Bubeck, R. A.; Fischer, D. A. Manuscript in preparation.
21. Stöhr, J. NEXAFS Spectroscopy; Springer-Verlag: Berlin, 1992.
22. Jäger, B.; Schürmann, H.; Müller, H. U.; Himmel, H.-J.; Neumann, M.; Grunze, M.; Wöll, C. Z. Phys. Chem. 1997, 202, 263. Wirde, M.; Gelius, U.; Dunbar, T.; Allara, D. L. Nucl. Instr. Methods Phys. Res. B 1997, 131, 245. Zharnikov, M.; Geyer, W.; Gölzhäuser, A.; Frey, S.; Grunze, M. Phys. Chem. Chem. Phys. 1999, 1, 3163.
23. Jäger, B.; Schürmann, H.; Müller, H. U.; Himmel, H.-J.; Neumann, M.; Grunze, M.; Wöll, C. Z. Phys. Chem. 1997, 202, 263. Wirde, M.; Gelius, U.; Dunbar, T.; Allara, D. L. Nucl. Instr. Methods Phys. Res. B 1997, 131, 245. Zharnikov, M.; Geyer, W.; Gölzhäuser, A.; Frey, S.; Grunze, M. Phys. Chem. Chem. Phys. 1999, 1, 3163.
24. Jäger, B.; Schürmann, H.; Müller, H. U.; Himmel, H.-J.; Neumann, M.; Grunze, M.; Wöll, C. Z. Phys. Chem. 1997, 202, 263. Wirde, M.; Gelius, U.; Dunbar, T.; Allara, D. L. Nucl. Instr. Methods Phys. Res. B 1997, 131, 245. Zharnikov, M.; Geyer, W.; Gölzhäuser, A.; Frey, S.; Grunze, M. Phys. Chem. Chem. Phys. 1999, 1, 3163.
25. Certain commercial equipment is identified in this article in order to specify adequately the experimental procedure. In no case does such identification imply recommendation or endorsement by the National Institute of Standards and Technology, nor does it imply that the items identified are necessarily the best available for the purpose.
26. Zisman, W. A. In Contact angle, wettability, and adhesion; American Chemical Society: Washington, DC, 1964.
27. The following liquids (surface tensions in mJ/m2) were used to measure O for the Zisman plots: tetradecane (26.7), dodecane (25.4), decane (23.9), nonane (22.9), octane 121.8), heptane (20.3), silicone oil DMS-T01 (17.4), and silicone oil DMS-T00 (15.8).
28. Outka, D.; Stöhr, J.; Rabe, J.; Swalen, J. D. J. Chem. Phys. 1988, 88, 4076.
29. Genzer, J.; Sivaniah, E.; Kramer, E. J.; Wang, J.; Char, K.; Ober, C. K.; DeKoven, B. M.; Fischer, D. A. Manuscript in preparation.
30. Matsen, M. W. J. Chem. Phys. 1997, 106, 7781 and references therein; Curr. Opin. Colloid Interface Sci. 1998, 3, 40 and references therein.
31. Matsen, M. W. J. Chem. Phys. 1997, 106, 7781 and references therein; Curr. Opin. Colloid Interface Sci. 1998, 3, 40 and references therein.
32. Genzer, J.; Sivaniah, E.; Kramer, E. J.; Xiang, M.; Char, K.; Ober, C. K.; Wang, J.; Graupe, M.; Colorado, R., Jr.; Shmakova, O. E.; Lee, T. R.; Chaudhury, M. K.; M.; Bubeck, R. A.; Sambasivan, S.; Fischer, D. A. Bull. Am. Phys. Soc. 1999, 44, 1451.
33. Lenk, T. J.; Hallmark, V. M.; Hoffmann, C. L.; Rabolt, J. F.; Castner, D. G.; Erdelen, C.; Ringsdorf, H. Langmuir 1994, 10, 4610.
34. Tsao, M.-W.; Hoffmann, C. L.; Rabolt, J. F.; Johnson, H. E.; Castner, D. G.; Erdelen, C.; Ringsdorf, H. Langmuir 1997, 13, 4317.
35. Grunze, M. Phys. Scr. 1993, T49, 711.
36. Nemetz, A.; Fischer, T.; Ulman, A.; Knoll, W. J. Chem. Phys. 1993, 98, 5912.
37. Ulman, A. Chem. Rev. 1996, 96, 1533.