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note
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Attempted copolymerisation of 4-vinylpyridine and styrene in the absence of silica at the same monomer concentration and pH produced a stable colloids solution.
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49
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0343779039
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note
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We are aware that the electrophoretic behaviour of conventional (co)polymer latexes prepared from persulfate initiators is strongly influenced by the surface sulfate groups derived from the initiator fragment. Since sulfate is a strong acid, this usually leads to negative ζ potentials over a rather wide range of pH. In the present system, the electrophoretic component from the anionic sulfate groups cannot be distinguished from that due to the anionic silanol groups due to the inorganic silica component. In other words, the sulfate groups are probably located at the surface of the (co)polymer-silica nanocomposite particles but their presence is not easily verified.
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50
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