Photochemical reactions of 2,6-bis(trimethylsilyl)-4H-pyran with α- ketoesters

Tetrahedron Letters

Volumn 41, Issue 27, 2000, Pages 5199-5202

  Saleur, Damien ^a   Bouillon, Jean Philippe ^a   Portella, Charles ^a   Hoffmann, Norbert ^a  

^a UNIVERSITÉ DE REIMS CHAMPAGNE ARDENNE   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ESTER; KETONE; PYRAN DERIVATIVE;

ARTICLE; CHEMICAL MODIFICATION; CHEMICAL REACTION; OXIDATION; PHOTOCHEMISTRY; REACTION ANALYSIS;

EID: 0034235419     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(00)00814-5     Document Type: Article

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10. 13C NMR).
11. -1): 3494, 1732, 1651, 1603.
12. -1): 1727, 1611. This oxidation by-product 3 was also observed when a solution of 4H-pyran 1 in AcOEt was stored at room temperature, under air atmosphere, during several days.
13. nJ) at 500 MHz spectrometer.
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