Oxyethylation and oxypropylation of alcohols of low relative molecular mass in the presence of amine-type catalysts

Journal of Chemical Technology and Biotechnology

Volumn 75, Issue 7, 2000, Pages 547-552

  Poskrobko, H ^a   Poskrobko, J ^a   Hreczuch, W ^a   Sobczynska A ^b   Szymanowski, J ^b  

^a INSTYTUT CI ZKIEJ SYNTEZY ORGANICZNEJ BLACHOWNIA   (Poland)

^b POZNAN UNIVERSITY OF TECHNOLOGY   (Poland)

Author keywords

[No Author keywords available]

Indexed keywords

AMINES; CATALYST SELECTIVITY; CATALYSTS; COMPOSITION EFFECTS; MOLECULAR WEIGHT; SYNTHESIS (CHEMICAL);

OXYETHYLATION; OXYPROPYLATION;

ALCOHOLS;

2 DIETHYLAMINOETHANOL; ALCOHOL; BUTANOL; DIETHYLAMINE; METHANOL; OXIDE; TRIETHYLAMINE;

CATALYST;

ALKYLATION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; MASS; MOLECULAR DYNAMICS; SYNTHESIS;

EID: 0034234506     PISSN: 02682575     EISSN: None     Source Type: Journal    
DOI: 10.1002/1097-4660(200007)75:7<547::AID-JCTB250>3.0.CO;2-N     Document Type: Article

References (12)

1. Schick MJ, Nonionic Surfactants, Marcel Dekker, New York (1967).
2. Bailey FE, Jr and Koleske JV, Alkylene Oxides and Their Polymers, Marcel Dekker, New York (1992).
3. Cox MF, The effect of peaking the ethylene oxide distribution on the performance of alcohol ethoxylates and ether sulfates: J Am Oil Chem Soc 67:599-604 (1990).
4. Smith DL, Comparison of salt thickening of conventional and peaked alcohol based sulfosuccinic acid halfesters. J Am Oil Chem Soc 68:629-633 (1991).
5. Hreczuch W and Szymanowski J, Synthesis of surfactants with narrow-range distribution of the polyoxyethylene chain. J Am Oil Chem Soc 73:73-78 (1996).
6. Hama I, Narrow alcohol ethoxylates, in Design and Selection of Performance Surfactants, Annual Surfactants Review, Ed by Karsa DR, Sheffield Academic Press, CRC Press, Sheffield. Vol 2, pp 146-167 (1999).
7. Santacesaria E, Iengo P and Serio MDi, Catalytic and kinetic effects in ethoxylation processes, in Design and Selection of Performance Surfactants, Annual Surfactants Review, Ed by Karsa DR, Sheffield Academic Press, CRC Press, Sheffield. Vol 2, pp 168-215 (1999).
8. Natta G and Mantica R, The distribution of products in a series of consecutive competive reactions. J Am Chem Soc 74:3152 (1952).
9. NM-CAD software, from JAMARO-Computer Application Laboratory, ul. Mostowa 3, 47-220 Kȩdzierzyn-Koźle, Poland.
10. Szymanowski J, Atamańczuk B and Szewczyk H, Molar mass distribution of polyoxyethylene derivatives of alcohols, alkylphenols and alkylamines. J Chem Technol Biotechnol 40:1-10 (1987).
11. Poskrobko J, Wasilewski J, Dziwiński E, Poskrobko H and Milchert E, By-products of alcohol ethoxylation in the presence of triethylamine. Tenside Surf Det 32:351-354 (1995).
12. Poskrobko J, Milchert E, Poskrobko H and Dziwiński E, By-products of ethoxylation of simple alcohols in the presence of tripropylamine. J Chem Technol Biotechnol 67:84-88 (1996).