Effect of solute concentration on hindered diffusion in porous membranes

AIChE Journal

Volumn 46, Issue 7, 2000, Pages 1307-1316

  Shao, Jiahui ^a   Baltus, Ruth E ^a  

^a Clarkson University   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COMPOSITION EFFECTS; MATHEMATICAL MODELS; PHASE EQUILIBRIA; POLYCARBONATES; POLYETHYLENE GLYCOLS; POLYMERIC MEMBRANES; SOLUTIONS; VAN DER WAALS FORCES;

CHAIN ENTANGLEMENT; DEXTRAN; DIFFUSION RATE; EQUILIBRIUM PARTITION COEFFICIENT; HINDERED DIFFUSION; INTRAPORE DIFFUSIVITY; POLYCARBONATE MEMBRANES; SOLUTE CONCENTRATION; VIRIAL COEFFICIENT;

DIFFUSION IN LIQUIDS;

DEXTRAN; MACROGOL;

CONCENTRATION; DIFFUSION; MEMBRANE;

ARTICLE; CONCENTRATION RESPONSE; DIFFUSION; MEMBRANE; MODEL; MOLECULAR INTERACTION; PARTITION COEFFICIENT; POROSITY;

EID: 0034233889     PISSN: 00011541     EISSN: None     Source Type: Journal    
DOI: 10.1002/aic.690460705     Document Type: Article

References (32)

1. Anderson, J. L., and R. P. Adamski, "Solute Concentration Effects on Membrane Reflection Coefficients," AIChE Symp. Ser., 79, 84 (1983).
2. Anderson, J. L., and J. H. Brannon, "Concentration Dependence of the Distribution Coefficient for Macromolecules in Porous Media," J. Poly. Sci.: Polym. Phys. Ed., 19, 405 (1981).
3. Bailey, F. E., Jr., and R. W. Callard, "Some Properties of Poly(ethylene oxide) in Aqueous Solution," J. Appl. Poly. Sci., 1, 56 (1959).
4. Batchelor, G. K., "Brownian Diffusion of Particles with Hydrodynamic Interaction," J. Fluid Mech., 74, 1 (1976).
5. Beenakker, C. W. J., and P. Mazur, "Diffusion of Spheres in Suspension: Three-Body Hydrodynamic Interaction Effects," Phys. Lett., 91, 290 (1982).
6. Berne, B., and R. Pecora, Dynamic Light Scattering, Wiley, New York, (1976).
7. Bhattacharjee, S., and A. Sharma, "Lifshitz-van der Waals Energy of Spherical Particles in Cylindrical Pores," J. Colloid Interface Sci., 171, 288 (1995).
8. Bleha, T., D. Bakos, and D. Berek, "Estimation of Thermodynamic Quality of the Solvent from the Concentration Effect in Gel Permeation Chromatography of Polymer," Polymer, 18, 897 (1977).
9. Brannon, J. H., and J. L. Anderson, "Concentration Effects on Partitioning of Dextrans and Serum Albumin," J. Poly. Sci.: Poly. Phys. Ed., 20, 857 (1982).
10. Cantow, M. J. R., et al., "Sample Concentration Effect in Gel Permeation Chromatography," J. Poly. Sci. Poly. Lett. Ed., 4, 707 (1966).
11. Chun, M. S., and R. J. Phillips, "Electrostatic Partitioning in Slit Pores by Gibbs Ensemble Monte Carlo Simulation," AIChE J., 43, 1194 (1997).
12. Deen, W. M., "Hindered Transport of Large Molecules in Liquid-Filled Pores" AIChE J., 33, 1409 (1987).
13. Devanand, K., and J. C. Selser, "Polyethylene Oxide Does Not Necessarily Aggregate in Water," Nature, 343, 739 (1990).
14. Glandt, E. D., "Distribution Equilibrium Between a Bulk Phase and Small Pores," AIChE J., 27, 51 (1981).
15. Graessley, W. W., "Polymer Chain Dimensions and the Dependence of Viscoelastic Properties on Concentration, Molecular Weight and Solvent Power," Polymer, 21, 258 (1980).
16. Hamaker, H. C., "The London-Van der Waals Attraction between Spherical Particles," Physica, 10, 1058 (1937).
17. Hiemenz, P. C., and R. Rajagopalan, Principles of Colloid and Surface Chemistry, 3rd ed., Marcel Dekker, New York (1997).
18. Israelachvili, J., "The Different Faces of Poly(ethylene glycol)," Proc. Nat. Acad. Sci., 94, 8378 (1997).
19. Johansson, L., C. Elvingson, and J.-E. Loftroth, "Diffusion and Interaction in Gels and Solutions. 2. Experimental Results on the Obstruction Effect," Macromol., 24, 6019 (1991).
20. Lepori, L., and V. Mollica, "Volumetric Properties of Dilute Aqueous Solutions of Poly(ethylene Glycols)," J. Poly. Sci., Poly. Phys. Ed., 16, 1123 (1978).
21. McQuarrie, D. A., Statistical Mechanics, Harper and Row, New York (1976).
22. Mitchell, B. D., and W. M. Deen, "Theoretical Effects of Macromolecular Concentration and Charge on Membrane Rejection Co-efficients," J. Memb. Sci., 19, 75 (1984).
23. Mitchell, B. D., and W. M. Deen, "Effects of Concentration on the Rejection Coefficients of Rigid Macromolecules in Track-Etch Membranes," J. Colloid Interface Sci., 113, 132 (1986).
24. Post, A. J., "Solute Partitioning between a Micropore and a Bulk Solution: A Linear Density Functional Approach," J. Colloid Interface Sci., 129, 451 (1989).
25. Post, A. J., and E. D. Glandt, "Equilibrium Partitioning in Pores with Adsorbing Walls," J. Colloid Interface Sci., 108, 31 (1985).
26. Post, A. J., and D. A. Kofke, "Fluids Confined to Narrow Pores: A Low-Dimensional Approach," Phys. Rev. A, 45, 939 (1992).
27. Rudin, A., "Concentration Effects in Gel-Permeation Chromatography," J. Poly. Sci., A-1, 9, 2587 (1971).
28. Satterfield, C. N., C. K. Colton, B. D. Turckheim, and T. M. Copeland, "Effect of Concentration on Partitioning of Polystyrene within Finely Porous Glass," AIChE J., 24, 937 (1978).
29. Selim, M. S., and M. A. Al-Naafa, "Brownian Diffusion of Hard Spheres at Finite Concentrations," AIChE J., 39, 4 (1993).
30. Shao, J., "The Effect of Solute Concentration on the Hindered Diffusion of Dextran and Polyethylene Glycol in Porous Membranes," PhD Diss., Clarkson Univ., Potsdam, NY (2000).
31. Shao, J. and R. E. Baltus, "Hindered Diffusion of Dextran and Polyethylene Glycol in Porous Membranes," AIChE J., in press (2000).
32. Singh, S., K. C. Khulbe, T. Matsuura, and P. Ramamurthy, "Membrane Characterization by Solute Transport and Atomic Force Microscopy," J. Memb. Sci., 142, 111 (1998).