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Volumn 113, Issue 1, 2000, Pages 434-446

Lattice model of living polymerization. III. Evidence for particle clustering from phase separation properties and 'rounding' of the dynamical clustering transition

Author keywords

[No Author keywords available]

Indexed keywords

ASSOCIATION REACTIONS; COMPRESSIBILITY OF LIQUIDS; CRYSTAL GROWTH; CRYSTAL LATTICES; DISSOCIATION; OSMOSIS; PHASE EQUILIBRIA; PHASE SEPARATION; PHASE TRANSITIONS; POLYMERIZATION; SPECIFIC HEAT OF LIQUIDS; TEMPERATURE;

EID: 0034229869     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.481808     Document Type: Article
Times cited : (77)

References (129)
  • 8
    • 4244212674 scopus 로고    scopus 로고
    • M. E. van Leeuwen and B. Smit, Phys. Rev. Lett. 71, 3991 (1993); Y. Levin, ibid. 83, 1159 (1999).
    • (1999) Phys. Rev. Lett. , vol.83 , pp. 1159
    • Levin, Y.1
  • 11
    • 0000690205 scopus 로고
    • E. de Miguel, L. F. Rull, and K. E. Gubbins, Physica A 177, 174 (1991); M. A. Osipov, P. I. C. Teixeira, and M. M. Telo da Gama, Phys. Rev. E 54, 2597 (1996); J. M. Tavares, J. J. Weis, and M. M. Telo da Gamma, ibid. 59, 4388 (1999).
    • (1991) Physica A , vol.177 , pp. 174
    • De Miguel, E.1    Rull, L.F.2    Gubbins, K.E.3
  • 12
    • 0001458704 scopus 로고    scopus 로고
    • E. de Miguel, L. F. Rull, and K. E. Gubbins, Physica A 177, 174 (1991); M. A. Osipov, P. I. C. Teixeira, and M. M. Telo da Gama, Phys. Rev. E 54, 2597 (1996); J. M. Tavares, J. J. Weis, and M. M. Telo da Gamma, ibid. 59, 4388 (1999).
    • (1996) Phys. Rev. E , vol.54 , pp. 2597
    • Osipov, M.A.1    Teixeira, P.I.C.2    Telo Da Gama, M.M.3
  • 13
    • 0001088393 scopus 로고    scopus 로고
    • E. de Miguel, L. F. Rull, and K. E. Gubbins, Physica A 177, 174 (1991); M. A. Osipov, P. I. C. Teixeira, and M. M. Telo da Gama, Phys. Rev. E 54, 2597 (1996); J. M. Tavares, J. J. Weis, and M. M. Telo da Gamma, ibid. 59, 4388 (1999).
    • (1999) Phys. Rev. E , vol.59 , pp. 4388
    • Tavares, J.M.1    Weis, J.J.2    Telo Da Gamma, M.M.3
  • 38
    • 0000130036 scopus 로고    scopus 로고
    • J. Dudowicz, K. F. Freed, and J. F. Douglas, J. Chem. Phys. 111, 7116 (1999); 112, 1002 (2000) are Papers I and 11, respectively, of the present series. These papers give numerous references to prior theoretical and experimental work on associating polymers. References 36 and 37 provide good recent reviews of equilibrium living polymerization from an experimental perspective.
    • (1999) J. Chem. Phys. , vol.111 , pp. 7116
    • Dudowicz, J.1    Freed, K.F.2    Douglas, J.F.3
  • 39
    • 0000968983 scopus 로고    scopus 로고
    • J. Dudowicz, K. F. Freed, and J. F. Douglas, J. Chem. Phys. 111, 7116 (1999); 112, 1002 (2000) are Papers I and 11, respectively, of the present series. These papers give numerous references to prior theoretical and experimental work on associating polymers. References 36 and 37 provide good recent reviews of equilibrium living polymerization from an experimental perspective.
    • (2000) J. Chem. Phys. , vol.112 , pp. 1002
  • 42
    • 6744252173 scopus 로고
    • R. S. Spangler, Phys. Rev. 46, 698 (1934); G. W. Stewart, Trans. Faraday Soc. 29, 982 (1933).
    • (1934) Phys. Rev. , vol.46 , pp. 698
    • Spangler, R.S.1
  • 43
  • 47
    • 84890181589 scopus 로고
    • G. Jackson, W. G. Chapman, and K. E. Gubbins, Mol. Phys. 65, 1 (1988); see also F. Dolezalek [Z. Phys. Chem. 64, 727 (1908)] for an early treatment of equilibrium particle association.
    • (1988) Mol. Phys. , vol.65 , pp. 1
    • Jackson, G.1    Chapman, W.G.2    Gubbins, K.E.3
  • 48
    • 84890181589 scopus 로고
    • G. Jackson, W. G. Chapman, and K. E. Gubbins, Mol. Phys. 65, 1 (1988); see also F. Dolezalek [Z. Phys. Chem. 64, 727 (1908)] for an early treatment of equilibrium particle association.
    • (1908) Z. Phys. Chem. , vol.64 , pp. 727
    • Dolezalek, F.1
  • 63
    • 0001211230 scopus 로고
    • S. Mal, P. Maiti, and A. K. Nandi, Macromolecules 28, 2371 (1995). Note the Arrhenius temperature dependence for critical gelation concentration found in this paper.
    • (1995) Macromolecules , vol.28 , pp. 2371
    • Mal, S.1    Maiti, P.2    Nandi, A.K.3
  • 69
    • 4244027337 scopus 로고
    • It is common in the experimental literature to identify the locus of temperatures and compositions at which "turbidity" occurs as the "cloud point curve" or "solubility curve." These phase diagrams do not always correspond to phase separation [G. D. J. Phillies, Phys. Rev. Lett. 55, 1341 (1985)]. The tendency of the "cloud point curve" to become independent of composition at high concentrations of the clustering species and the absence of macroscopic phase separation into coexisting phases are symptomatic of a "clustering transition" rather than a phase separation.
    • (1985) Phys. Rev. Lett. , vol.55 , pp. 1341
    • Phillies, G.D.J.1
  • 77
    • 6744232615 scopus 로고    scopus 로고
    • Note the Arrhenius temperature dependence of the critical micelle concentration in Refs. 66-70
    • Note the Arrhenius temperature dependence of the critical micelle concentration in Refs. 66-70.
  • 103
    • 0028764211 scopus 로고
    • A. P. Andrews, K. P. Andrews, S. C. Greer, F. Boue, and P. Pfeuty, Macromolecules 27, 3902 (1994). Some differences exist between our calculations of I(0) and the spin model calculations of I(0) by Andrews et al. The two mean-field models coincide in very high and low temperatures, but discrepancies remain at intermediate temperatures. Unfortunately, Ref. 96 provides insufficient details for us to recognize the source of this discrepancy.
    • (1994) Macromolecules , vol.27 , pp. 3902
    • Andrews, A.P.1    Andrews, K.P.2    Greer, S.C.3    Boue, F.4    Pfeuty, P.5
  • 113
    • 0021408850 scopus 로고
    • M. S. Wertheim, J. Stat. Phys. 35, 19 (1984); 35, 35 (1984); 42, 459 (1986); 42, 477 (1986); J. Chem. Phys. 85, 2929 (1986); 87, 7323 (1987).
    • (1984) J. Stat. Phys. , vol.35 , pp. 19
    • Wertheim, M.S.1
  • 114
    • 0021408850 scopus 로고
    • M. S. Wertheim, J. Stat. Phys. 35, 19 (1984); 35, 35 (1984); 42, 459 (1986); 42, 477 (1986); J. Chem. Phys. 85, 2929 (1986); 87, 7323 (1987).
    • (1984) J. Stat. Phys. , vol.35 , pp. 35
  • 115
    • 13444285081 scopus 로고
    • M. S. Wertheim, J. Stat. Phys. 35, 19 (1984); 35, 35 (1984); 42, 459 (1986); 42, 477 (1986); J. Chem. Phys. 85, 2929 (1986); 87, 7323 (1987).
    • (1986) J. Stat. Phys. , vol.42 , pp. 459
  • 116
    • 0342653160 scopus 로고
    • M. S. Wertheim, J. Stat. Phys. 35, 19 (1984); 35, 35 (1984); 42, 459 (1986); 42, 477 (1986); J. Chem. Phys. 85, 2929 (1986); 87, 7323 (1987).
    • (1986) J. Stat. Phys. , vol.42 , pp. 477
  • 117
    • 0000350011 scopus 로고
    • M. S. Wertheim, J. Stat. Phys. 35, 19 (1984); 35, 35 (1984); 42, 459 (1986); 42, 477 (1986); J. Chem. Phys. 85, 2929 (1986); 87, 7323 (1987).
    • (1986) J. Chem. Phys. , vol.85 , pp. 2929
  • 118
    • 0011775424 scopus 로고
    • M. S. Wertheim, J. Stat. Phys. 35, 19 (1984); 35, 35 (1984); 42, 459 (1986); 42, 477 (1986); J. Chem. Phys. 85, 2929 (1986); 87, 7323 (1987).
    • (1987) J. Chem. Phys. , vol.87 , pp. 7323
  • 126
    • 6744254759 scopus 로고    scopus 로고
    • Oxford University Press, New York
    • The concept of a phase transition is an ideal "Form" in the sense of Plato [Phaedo (Oxford University Press, New York, 1999)]. Forms are never realized in the physical world, but can be approximated to a greater or lesser degree by a physical system.
    • (1999) Phaedo
    • Plato1


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