Luminescence thermochromism in dicyanoargentate(i) ions doped in alkali halide crystals

Journal of Physical Chemistry B

Volumn 104, Issue 26, 2000, Pages 6143-6151

  Rawashdeh Omary, Manal A ^a,c   Omary, Mohammad A ^a,c   Shankle, George E ^b   Patterson, Howard H ^a,c  

^a UNIVERSITY OF MAINE   (United States)

^b ANGELO STATE UNIVERSITY   (United States)

^c TEXAS A AND M UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION SPECTROSCOPY; ATOMIC SPECTROSCOPY; EMISSION SPECTROSCOPY; ENERGY GAP; ISOMERS; KINETIC THEORY; LUMINESCENCE; MATHEMATICAL MODELS; SINGLE CRYSTALS; THERMAL EFFECTS; ULTRAVIOLET RADIATION;

ALKALI HALIDES; EXCIPLEX TUNING; LUMINESCENCE THERMOCHROMISM;

PHOTOCHROMISM;

EID: 0034228655     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp000563x     Document Type: Article

References (87)

1. Jansen, M. Angew. Chem., Int. Ed. Engl. 1987, 26, 1098.
2. Kutal, C. Coord. Chem. Rev. 1990, 99, 213.
3. Ford, P. C.; Vogler, A. Acc. Chem. Res. 1993, 26, 220.
4. (a) De Ahna, H. D.; Hardt, H. D. Z. Anorg. Allg. Chem. 1972, 387, 61.
5. (b) Hardt, H. D.; Gechnizdjani, H. Anorg. Allg. Chem. 1973, 397, 23.
6. (c) Hardt, H. D.; Pierre, A. Anorg. Allg. Chem. 1973, 402, 107.
7. (d) Hardt, H. D.; Pierre, A. Inorg. Chim. Acta 1977, 25, L59.
8. (e) Hardt, D. D.; Stoll, H. J. Z. Anorg. Allg. Chem. 1981, 480, 193.
9. Hardt, D. D.; Stoll, H. J. Z. Anorg. Allg. Chem. 1981, 480, 199.
10. (a) Kyle, K. R.; Ryu, C. K.; DiBenedetto, J. A.; Ford, P. C. J. Am. Chem. Soc. 1991, 113, 2954.
11. (b) Kyle, K. R.; DiBenedetto, J. A.; Ford, P. C. J. Chem. Soc., Chem. Commun. 1989, 714.
12. (c) Kyle, K. R.; Ford, P. C. J. Am. Chem. Soc. 1989, 111, 5005.
13. (d) Kyle, K. R.; Palke, W. E.; Ford, P. C. Coord. Chem. Rev. 1990, 97, 35.
14. (e) Døssing, A.; Ryu, C. K.; Kudo, S.; Ford, P. C. J. Am. Chem. Soc. 1993, 115, 5132.
15. (f) Ford, P. C. Coord. Chem. Rev. 1994, 132, 129.
16. (g) Tran, D.; Ryu, C. K.; Ford, P. C. Inorg. Chem. 1994, 33, 56.
17. (h) Simon, J. A.; Palke, W. E.; Ford, P. C. Inorg. Chem. 1996, 35, 6413.
18. (i) Vitale, M.; Palke, W. E.; Ford, P. C. J. Phys. Chem. 1992, 96, 8329.
19. (j) Vitale, M.; Ryu, C. K.; Palke, W. E.; Ford, P. C. Inorg. Chem. 1994, 33, 561.
20. Schmidbaur, H. Chem. Soc. Rev. 1995, 391.
21. Omary, M. A.; Webb, T. R.; Assefa, Z.; Shankle, G. E.; Patterson, H. H. Inorg. Chem. 1998, 37, 1380.
22. Omary, M. A.; Patterson, H. H. J. Am. Chem. Soc. 1998, 120, 7696.
23. Omary, M. A.; Patterson, H. H. Inorg. Chem. 1998, 37, 1060.
24. Edel, A.; Marnot, P. A.; Sauvage, J. P. Nouv. J. Chim. 1984, 8, 495.
25. (a) Zecchina, A.; Bordiga, S.; Palomino, G. T.; Scarano, D.; Lamberti, C.; Salvalaggio, M. J. Phys. Chem. B. 1999, 103, 3833.
26. (b) Shelef, M. Chem. Rev. 1995, 95, 209.
27. (a) Kruglik, G. S.; Skripko, G. A.; Shkadarevich, A. P.; Ermolenko, N. N.; Gorodetskaya, O. G.; Belokon, M. V.; Shagov, A. A.; Zolotareva, L. E. Opt. Spectrosc. (U.S.S.R.) 1985, 59, 439.
28. (b) Moine, B.; Pedrini, C.; Duloisy, E.; Boutinaud, P.; Parent, C.; Le Flem, G. J. Physique IV 1991, C7, 289.
29. Blonder, R.; Levi, S.; Tao, G.; Ben-Dov, I.; Willner, I. J. Am. Chem. Soc. 1997, 119, 10467.
30. Wolf, M. O.; Fox, M. A. J. Am. Chem. Soc. 1995, 117, 1845.
31. (a) Roy, P. W.; Elder, R. C.; Tepperman, K. Metal Based Drugs 1994, 1, 521.
32. (b) Walz, D. T. In Advances in Inflammation Research; Otterness, I., Capetola, R., Wond, S., Eds.; Raven Press: New York, 1984; Vol. 7, p 239.
33. (c) Sutton, B. M.; McCusty, E.; Walz, D. T.; DiMartino, M. J. J. Med. Chem. 1972, 15, 1095.
34. Mansour, M. A.; Connick, W. B.; Lachicotte, R. J.; Gysling, H. J.; Eisenberg, R. J. Am. Chem. Soc. 1998, 120, 1329.
35. (a) Von der Austin, W.; Stolz, H. J. Phys. Chem. Solids 1990, 51, 765.
36. (b) Hamilton, J. F. Adv. Phys. 1988, 37, 359.
37. (c) Ueta, M.; Kanzaki, H.; Kabayashi, K.; Toyozawa, Y.; Hanamura, E. Excitonic Processes in Solids; Springer: Berlin; 1986; pp 309-69.
38. Moser, F.; Barkay, N.; Levite, A.; Margalit, E.; Paiss, I.; Sa'ar, A.; Schnitzer, I.; Zur, A.; Katzir, A. Proc. SPIE 1990, 1228, 128.
39. (a) Anpo, M.; Matsuoka, M.; Mishima, H.; Yamashita, H. Res. Chem. Intermed. 1997, 23, 197.
40. (b) Anpo, M.; Matsuoka, M.; Yamashita, H. Catal. Today 1997, 35, 177.
41. (c) Kanan, S. M.; Omary, M. A.; Patterson, H. H.; Matsuoka, M.; Anpo, M. J. Phys. Chem. B 2000, 104, 3507.
42. Köhler, B. U.; Weppner, W.; Jansen, M. J. Solid State Chem. 1985, 57, 227.
43. Gruber, H.; Hess, H.; Popitsch, A.; Fischer, A. P. J. Electrochem. Soc. 1982, 129, 369.
44. Popitsch, A. J. Crystallogr. Spectrosc. Res. 1985, 15, 603.
45. (a) Lowry, T. H.; Schuller-Richardson, K. Mechanism and Theory in Organic Chemistry; Harper&Row: New York, 1981; pp 919-925.
46. (b) Turro, N. J. Modem Molecular Photochemistry; Benjamin/Cummings: Melano Park, CA, 1978; pp 135-146.
47. (c) Lamola, A. A. In Energy Transfer and Organic Photochemistry; Lamola, A. A., Turro, N. J., Eds.; Wiley-Interscience: New York, 1969; pp 54-60.
48. (d) The Exciplex; Gordon, M., Ware, W. R., Eds.; Academic Press: New York, 1975.
49. (e) Kopecky, J. Organic Photochemistry: A Visual Approach; VCH: New York, 1991; pp 38-40.
50. (f) Michl, J.; Bonacic-Koutecky, V. Electronic Aspects of Organic Photochemistry; Wiley: New York, 1990; pp 274-286.
51. (a) For a recent review see: Horváth, A.; Stevenson, K. L. Coord Chem. Rev. 1996, 153, 57.
52. m]. An excimer is a subcategory for the general term "exciplex", in which A = B and n = m = 1: Omary, M. A.; Patterson, H. H. Electronic Spectroscopy: Luminescence Theory: Encyclopedia of Spectroscopy & Spectrometry; Academic Press: London, UK, 2000; pp 1186-1207.
53. Omary, M. A.; Hall, D. R.; Shankle, G. E.; Siemiarczuck, A.; Patterson, H. H. J. Phys. Chem. B 1999, 103, 3845.
54. Melhuish, W. H. J. Opt. Soc. Am. 1962, 52, 1256.
55. -]/ KCl.
56. (b) We have carried out a systematic concentration-dependent luminescence study in solution, in which the concentration is varied gradually over several orders of magnitude (ref 29; Omary, M. A. R.; Omary, M. A.; Patterson, H. H., submitted for publication). The trends obtained for the three doped crystals mentioned here are reproduced in the solution study.
57. -] (see ref 29).
58. Omary, M. R. Ph.D. Thesis, Graduate School, University of Maine, 1999.
59. Omary, M. A.; Patterson, H. H.; Shankle, G. Mol. Cryst. Uq. Cryst. 1996, 284, 399.
60. (a) Nagle, J. K.; LaCasce, J. H., Jr.; Dolan, P. J., Jr.; Corson, M. R.; Assefa, Z.; Patterson, H. H. Mol. Cryst. Uq. Cryst. 1990, 181, 359.
61. (b) Patterson, H. H.; Roper, G.; Biscoe, J.; Ludi, A.; Blom, N. J. Lumin. 1984, 31/32, 555.
62. (c) Markert, J. T.; Blom, N.; Roper, G.; Perregaux, A. D.; Nagasundaram, N.; Corson, M. R.; Ludi, A.; Nagle, J. K.; Patterson, H. H. Chem. Phys. Lett. 1985, 118, 258.
63. (d) LaCasce, J. H., Jr.; Turner, W. A.; Corson, M. R.; Dolan, P. J., Jr.; Nagle, J. K. Chem. Phys. 1987, 118, 289.
64. (a) Yersin, H.; Gliemann, G. Ann. N.Y. Acad. Sci. 1978, 313, 539.
65. (b) Gliemann, G.; Yersin, H. Struct. Bonding 1985, 62, 87.
66. Yersin, H.; Riedl, U. Inorg. Chem. 1995, 34, 1642.
67. Connick, W. B.; Henling, L. M.; Marsh, R. E.; Gray, H. B. Inorg. Chem. 1996, 35, 6261.
68. Omary, M.; Patterson, H. H.; Eckert, J.; Jacubinas, R. Unpublished results.
69. Larochelle, C. L.; .Omary, M. A.; Patterson, H. H.; Fischer, P.; Fauth, F.; Allenspach, P.; Lucas, B.; Pattison, P. Solid State Commun. 2000, 114, 155.
70. Omary, M. A. Ph.D. Thesis, Graduate School, University of Maine, 1997.
71. Kambli, U.; Güdel, H. U. Inorg. Chem. 1984, 23, 3479.
72. Omary, M. A. R.; Larochelle, C. L.; Patterson, H. H. Tunable Energy Transfer from Dicyanoaurate(I) and Dicyanoargentate(I) Donor Ions to Tb(III) Acceptor Ions in Pure Crystals, submitted for publication.
73. This assumption is also reasonable because of the presence of isoluminescent points between bands A and B as well as between C and D (for example note the two isoluminescent points at ca. 307 and 322 nm between bands A and B in Figure 4). This indicates equilibrium between the two excitons responsible for these bands.
74. Freed, K. F.; Jortner, J. J. Chem. Phys. 1970, 52, 6272.
75. Riesen, H.; Güdel, H. U. Chem. Phys. Lett. 1987, 133, 429.
76. Yersin, H.; Gallhuber, E.; Hensler, G. Chem. Phys. Lett. 1987, 140, 157.
77. (a) Zink, J. I.; Shin, K. S. K. Molecular Distortions in Excited Electronic States Determined from Electronic and Resonance Roman Spectroscopy. In Advances in Photochemistry; Volman, D. H., Hammond, G. S., Neckers, D. C., Eds.; Wiley: New York, 1991; Vol. 16.
78. (b) Tutt, L.; Zink, J. I. J. Am. Chem. Soc. 1986, 108, 5830.
79. (c) Preston, D. M.; Guentner, W.; Lechner, A.; Gliemann, G.; Zink, J. I. J. Am. Chem. Soc. 1988, 110, 5628.
80. (d) Hollingsworth, G.; Shin, K. S. K.; Zink, J. I. Inorg. Chem. 1990, 29, 2501.
81. (a) Wong, P. T. T. J. Chem. Phys. 1979, 70, 456.
82. (b) Bottger, G. L.; Spectrochim. Acta Part A 1968, 24, 1821.
83. (c) Loehr, T. M.; Long, T. V., II. J. Chem. Phys. 1970, 53, 4182.
84. (d) Chadwick, B. M.; Frankiss, S. G. J. Mol. Struct. 1968, 2, 281.
85. (a) Gebhardt, W.; Kühnert, H. Phys. Lett. 1964, 11, 15.
86. (b) For a review see: Markham, J. J. F-Centers in Alkali Halides; Academic Press: New York and London, 1966; Chapter X.
87. For a discussion of light sources in optical instruments, see: Skoog, D. A.; Holler, F. J.; Nieman, T. A. Principles of Instrumental Analysis, 5th ed.; Harcourt Brace: Philadelphia, 1998.