Versatile initiators for macromonomer syntheses of acrylates, methacrylates, and styrene by atom transfer radical polymerization

Macromolecules

Volumn 33, Issue 15, 2000, Pages 5399-5404

  Shen, Youqing ^a   Zhu, Shiping ^a   Zeng, Faquan ^a   Pelton, Robert ^a  

^a MCMASTER UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; COMPOSITION EFFECTS; FREE RADICAL POLYMERIZATION; INITIATORS (CHEMICAL); MOLECULAR STRUCTURE; MOLECULAR WEIGHT; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYACRYLATES; POLYSTYRENES; REACTION KINETICS; SYNTHESIS (CHEMICAL);

ATOM TRANSFER RADICAL POLYMERIZATION (ATRP); MACROMONOMERS; POLYMETHACRYLATE;

MONOMERS;

EID: 0034228597     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma000201n     Document Type: Article

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17. The polymerization of 2-(dimethylamino)ethyl vinyl ether was tried with the same catalyst system. 19.8 mg of CuBr, 31.6 mg of HMTETA, 2 mL of (dimethylamino)ethyl vinyl ether, 1 mL of γ-EL, and 20 μL of ethyl 2-bromoisobutyrate were charged to a tube and degassed by nitrogen. The mixture was heated to 60°C for 24 h. No polymer was isolated. Then 1.5 mL of degassed MA was injected to the polymerization media. No polymer was found either. The same result was obtained using 2-hydroxylethyl vinyl ether as a monomer.