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Volumn 19, Issue 14, 2000, Pages 2658-2660

A new η6-anthraceno-diphosphine-silver(i) complex and molecular light switch effect

Author keywords

[No Author keywords available]

Indexed keywords

CHLORINE COMPOUNDS; COMPLEXATION; CRYSTAL STRUCTURE; MOLECULAR DYNAMICS; MOLECULAR SPECTROSCOPY; MOLECULAR STRUCTURE; PHOTOLUMINESCENCE; SOLUTIONS; STOICHIOMETRY; X RAY CRYSTALLOGRAPHY;

EID: 0034228418     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9909237     Document Type: Article
Times cited : (43)

References (21)
  • 7
    • 33745895193 scopus 로고    scopus 로고
    • note
    • A solution of Ph2PCl (1.21 g, 5.5 mmol) in anhydrous benzene (20 mL) was added with stirring to 9, 10-bis(propaminomethyl)anthracene (0.80 g, 2.5 mmol) and triethylamine (1.0 g, 9.6 mmol) in anhydrous benzene (20 mL) at 0 °C. The mixture was stirred for 7 h at room temperature. The solvent was removed under vacuum, CH2C12 (30 mL) was added, and the solid was removed by filtration. The filtrate was concentrated to about 10 mL, and subsequently diethyl ether was added to give a yellow solid. The product was recrystallized from CH2C12 and ether (3:1) (0.94 g, 54.5%). Selected data for 1: mp 171-172 °C; *H NMR (CDC13) <5 0.25-0.42 (t, 6H, 2CH3), 2.76-3.00 (m, 4H, 2CH2), 0.70-1.10 (m, 4H, 2CH2), 5.26 (s, 4H, 2CH2), 7.407.48 (m, 20H, 2Ph), 7.77-7.87 (m, 4H, 2CH), 8.60-8.70 (m, 4H, 2CH); 31P{'H} NMR (CDC13) <5 55.73 (s, 2P). Anal. Calcd for CisHeN: C, 80.03; H, 6.73; N, 4.27. Found: C, 80.21; H, 6.85; N, 4.07.
  • 8
    • 33947336923 scopus 로고    scopus 로고
    • 1966, SS, 3243.
    • (a) Turner, R. W.; Amma, E. L. J. Am. Chem. Soc. 1966, SS, 3243.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.