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Volumn 19, Issue 14, 2000, Pages 2661-2663

Allyl/alkyne coupling reactions mediated by neutral ruthenium(II). Isolation and characterization of ruthenium(II) η3-allyl η2-alkyne complexes

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; CHEMICAL BONDS; COMPLEXATION; CRYSTALLIZATION; REACTION KINETICS; SUBSTITUTION REACTIONS; SYNTHESIS (CHEMICAL); TRANSITION METALS; X RAY CRYSTALLOGRAPHY;

EID: 0034224967     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om000275n     Document Type: Article
Times cited : (17)

References (64)
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    • Complete experimental and characterization data are provided as Supporting Information.
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    • For most disubstituted alkynes, the presence of excess alkyne has no significant effect on the course of the reaction. However, the reactions of acetylene, dimethyl acetylenedicarboxylate, and ethyl 2-butynoate under these conditions proceed via alternative reactivity patterns. These reactions will be discussed in a separate account: Older, C. M.; Stryker, J. M. Manuscript in preparation
    • For most disubstituted alkynes, the presence of excess alkyne has no significant effect on the course of the reaction. However, the reactions of acetylene, dimethyl acetylenedicarboxylate, and ethyl 2-butynoate under these conditions proceed via alternative reactivity patterns. These reactions will be discussed in a separate account: Older, C. M.; Stryker, J. M. Manuscript in preparation.
  • 59
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    • For both complexes 3a and 3b, the vinyl olefin intermediate can be trapped upon addition of carbon monoxide
    • For both complexes 3a and 3b, the vinyl olefin intermediate can be trapped upon addition of carbon monoxide.
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    • 2-TMSC≡CTMS) (3d) results in the formation of several unidentified products
    • 2-TMSC≡CTMS) (3d) results in the formation of several unidentified products.
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    • 5-pentadienyl complexes
    • 5-pentadienyl complexes.
  • 63
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    • agostic)
    • agostic).


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