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0343924024
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Fürstner, A., Ed.; VCH: New York, Chapter 1
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Rieke, R.D.1
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Hanson, M.V.6
-
42
-
-
0343052356
-
-
2, but the reaction proceeds much more slowly
-
2, but the reaction proceeds much more slowly.
-
-
-
-
43
-
-
0343488136
-
-
Complete experimental and characterization data are provided as Supporting Information
-
Complete experimental and characterization data are provided as Supporting Information.
-
-
-
-
44
-
-
0342618094
-
-
note
-
1H} NMH (75 MHz) δ 132.5, 132.3, 128.3, 126.3, 98.1, 94.1, 79.6, 44.8, 9.7.
-
-
-
-
45
-
-
33746570510
-
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13C NMR chemical shifts for coordinated alkynes: Templeton, J. L. Adv. Organomet. Chem. 1989, 29, 1. Kowalczyk, J. J.; Arif, A. M.; Gladysz, J. A. Organometallics 1991, 10, 1079. Templeton, J. L.; Ward, B. C. J. Am. Chem. Soc. 1980, 102, 3288. See also: Cooke, J.; Takats, J. J. Am. Chem. Soc. 1997, 119, 11088 and references therein. Werner, H.; Baum, M.; Schneider, D.; Windmüller, B. Organometallics 1994, 13, 1089.
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13C NMR chemical shifts for coordinated alkynes: Templeton, J. L. Adv. Organomet. Chem. 1989, 29, 1. Kowalczyk, J. J.; Arif, A. M.; Gladysz, J. A. Organometallics 1991, 10, 1079. Templeton, J. L.; Ward, B. C. J. Am. Chem. Soc. 1980, 102, 3288. See also: Cooke, J.; Takats, J. J. Am. Chem. Soc. 1997, 119, 11088 and references therein. Werner, H.; Baum, M.; Schneider, D.; Windmüller, B. Organometallics 1994, 13, 1089.
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13C NMR chemical shifts for coordinated alkynes: Templeton, J. L. Adv. Organomet. Chem. 1989, 29, 1. Kowalczyk, J. J.; Arif, A. M.; Gladysz, J. A. Organometallics 1991, 10, 1079. Templeton, J. L.; Ward, B. C. J. Am. Chem. Soc. 1980, 102, 3288. See also: Cooke, J.; Takats, J. J. Am. Chem. Soc. 1997, 119, 11088 and references therein. Werner, H.; Baum, M.; Schneider, D.; Windmüller, B. Organometallics 1994, 13, 1089.
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Templeton, J.L.1
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48
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0030669208
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and references therein
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13C NMR chemical shifts for coordinated alkynes: Templeton, J. L. Adv. Organomet. Chem. 1989, 29, 1. Kowalczyk, J. J.; Arif, A. M.; Gladysz, J. A. Organometallics 1991, 10, 1079. Templeton, J. L.; Ward, B. C. J. Am. Chem. Soc. 1980, 102, 3288. See also: Cooke, J.; Takats, J. J. Am. Chem. Soc. 1997, 119, 11088 and references therein. Werner, H.; Baum, M.; Schneider, D.; Windmüller, B. Organometallics 1994, 13, 1089.
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Cooke, J.1
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0001487995
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13C NMR chemical shifts for coordinated alkynes: Templeton, J. L. Adv. Organomet. Chem. 1989, 29, 1. Kowalczyk, J. J.; Arif, A. M.; Gladysz, J. A. Organometallics 1991, 10, 1079. Templeton, J. L.; Ward, B. C. J. Am. Chem. Soc. 1980, 102, 3288. See also: Cooke, J.; Takats, J. J. Am. Chem. Soc. 1997, 119, 11088 and references therein. Werner, H.; Baum, M.; Schneider, D.; Windmüller, B. Organometallics 1994, 13, 1089.
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Werner, H.1
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50
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0343052350
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12
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12
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51
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33845559268
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Schilling, B. E. R.; Hoffmann, R.; Lichtenberger, D. L. J. Am. Chem. Soc. 1979, 101, 585. Silvestre, J.; Hoffmann, R. Helv. Chim. Acta 1985, 68, 1461. Bruce, M. I. Chem. Rev. 1991, 91, 7. Lomprey, J. L.; Selegue, J. P. J. Am. Chem. Soc. 1992, 114, 5518.
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Schilling, B. E. R.; Hoffmann, R.; Lichtenberger, D. L. J. Am. Chem. Soc. 1979, 101, 585. Silvestre, J.; Hoffmann, R. Helv. Chim. Acta 1985, 68, 1461. Bruce, M. I. Chem. Rev. 1991, 91, 7. Lomprey, J. L.; Selegue, J. P. J. Am. Chem. Soc. 1992, 114, 5518.
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Silvestre, J.1
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Schilling, B. E. R.; Hoffmann, R.; Lichtenberger, D. L. J. Am. Chem. Soc. 1979, 101, 585. Silvestre, J.; Hoffmann, R. Helv. Chim. Acta 1985, 68, 1461. Bruce, M. I. Chem. Rev. 1991, 91, 7. Lomprey, J. L.; Selegue, J. P. J. Am. Chem. Soc. 1992, 114, 5518.
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Schilling, B. E. R.; Hoffmann, R.; Lichtenberger, D. L. J. Am. Chem. Soc. 1979, 101, 585. Silvestre, J.; Hoffmann, R. Helv. Chim. Acta 1985, 68, 1461. Bruce, M. I. Chem. Rev. 1991, 91, 7. Lomprey, J. L.; Selegue, J. P. J. Am. Chem. Soc. 1992, 114, 5518.
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Lomprey, J.L.1
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55
-
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0343924015
-
-
For most disubstituted alkynes, the presence of excess alkyne has no significant effect on the course of the reaction. However, the reactions of acetylene, dimethyl acetylenedicarboxylate, and ethyl 2-butynoate under these conditions proceed via alternative reactivity patterns. These reactions will be discussed in a separate account: Older, C. M.; Stryker, J. M. Manuscript in preparation
-
For most disubstituted alkynes, the presence of excess alkyne has no significant effect on the course of the reaction. However, the reactions of acetylene, dimethyl acetylenedicarboxylate, and ethyl 2-butynoate under these conditions proceed via alternative reactivity patterns. These reactions will be discussed in a separate account: Older, C. M.; Stryker, J. M. Manuscript in preparation.
-
-
-
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56
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0012780641
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(a) Trakarnpruk, W.; Arif, A. M.; Ernst, R. D. Organometallics 1994, 13, 2423.
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Trakarnpruk, W.1
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57
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0001524455
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(b) Trakarnpruk, W.; Arif, A. M.; Ernst, R. D. Organometallics 1992, 11, 1686.
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Trakarnpruk, W.1
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58
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0000041734
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(c) Bosch, H. W.; Hund, H.-U.; Nietlispach, D.; Salzer, A. Organometallics 1992, 11, 2087.
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Bosch, H.W.1
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Salzer, A.4
-
59
-
-
0343924017
-
-
For both complexes 3a and 3b, the vinyl olefin intermediate can be trapped upon addition of carbon monoxide
-
For both complexes 3a and 3b, the vinyl olefin intermediate can be trapped upon addition of carbon monoxide.
-
-
-
-
60
-
-
0343052347
-
-
2-TMSC≡CTMS) (3d) results in the formation of several unidentified products
-
2-TMSC≡CTMS) (3d) results in the formation of several unidentified products.
-
-
-
-
61
-
-
0343488130
-
-
5-pentadienyl complexes
-
5-pentadienyl complexes.
-
-
-
-
64
-
-
0342618090
-
-
agostic)
-
agostic).
-
-
-
|