A new nine-membered triphosphorus macrocycle

Organometallics

Volumn 19, Issue 14, 2000, Pages 2652-2654

  Edwards, Peter G ^a   Whatton, Mark L ^a   Haigh, Robert ^a  

^a CARDIFF UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYLATION; COMPLEXATION; HYDROGENATION; IRON COMPOUNDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; STRUCTURE (COMPOSITION); SYNTHESIS (CHEMICAL);

DIPHOSPHINOBENZENE; TRIVINYLPHOSPHINE;

PHOSPHORUS COMPOUNDS;

EID: 0034224139     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0002879     Document Type: Article

References (18)

1. (a) Diel, B. N.; Brandt, P. F.; Haltiwanger, R. C.; Hackney, L. J.; Norman, A. D. Inorg, Chem. 1989, 28, 2811.
2. (b) Edwards, P. G.; Fleming, J. S.; Liyanage, S. S. Inorg. Chem. 1996, 35, 4563.
3. Kyba, E. P.; Davis, R. E.; Liu, S.-T.; Hasset, K. A.; Larson, S. B. Inorg. Chem. 1985, 24, 4629.
4. For a review of the chemistry of triazacyclononane see: Chaudhuri, J.; Weighardt, K. In Progress in Inorganic Chemistry, Lippard, S. J., Ed.; Wiley: Chichester, U.K., 1987; Vol. 35, p 329.
5. Edwards, P. G.; Fleming, J. S.; Liyanage, S. S.; Coles, S. J.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1996, 1801.
6. (a) Crisp, G. T.; Salem, G.; Wild, S. B. Organometallics 1989,8, 2360.
7. (b) Bader, A.; Kang, Y. B.; Fabel, M.; Pathak, D. D.; Willis, A. C.; Wild, S. B. Organometallics 1995, 14, 1434.
8. Catheline, D.; Astruc, D. Organometallics 1984, 3, 1094.
9. Kyba, E. P.; Liu, S.-T.; Harris, R. L. Organometallics 1983, 2, 1877.
10. P-H = 341 Hz). Anal. Calcd (found): C, 41.7 (41.9); H, 5.0 (5.3).
11. Kaesz, H. D.; Stone, F. G. A. J. Org. Chem. 1959, 24, 635.
12. +). Anal. Calcd (found): C, 44.8 (44.9); H, 5.4 (5.3).
13. +). Anal. Calcd (found): C, 44.6 (44.5); H, 5.8 (5.7).
14. +). Anal. Calcd (found): C, 48.2 (48.4); H, 6.5 (6.4).
15. 15 using all unique data. All non-hydrogen atoms are anisotropic, with H atoms included in calculated positions (riding model). Empirical absorption corrections were carried out by the DIFABS method.16 Compound 6 crystallized with two crystallographically independent molecules in the asymmetric unit. There are no significant geometric differences between the two molecules, and the molecular structure of only one of them is shown in Figure 1.
16. Jones, D. J.; Edwards, P. G.; Tooze, R. P.; Albers, T. J. Chem. Soc. Dalton Trans. 1996, 1801.
17. Sheldrick, G. M.; SHELX97; University of Göttingen, Göttingen, Germany, 1997.
18. Walker, N. P. C.; Stuart, D. Acta Crystallogr., Sect. A 1983, 39, 158.