Lewis acid-mediated ring expansion reaction of benzo[b]cyclopropa[e]pyran-7-ol acetates: Facile synthesis of 2-alkyl substituted 2,3-dihydro-1-benzoxepins

Heterocycles

Volumn 53, Issue 6, 2000, Pages 1251-1254

  Sugita, Yoshiaki ^a   Hosoya, Hiroki ^a   Yokoe, Ichiro ^a  

^a JOSAI UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

BENZOXEPIN DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; ELECTRON TRANSPORT; JAPAN; MOLECULAR INTERACTION; SYNTHESIS;

EID: 0034210683     PISSN: 03855414     EISSN: None     Source Type: Journal    
DOI: 10.3987/COM-00-8882     Document Type: Article

References (25)

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3. Similar type of ring expansion reaction using cyclopropanated carbohydrates has been reported. J. O. Hoberg, J. Org. Chem., 1991, 62, 6615.
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25. 4, and the solvent was evaporated under reduced pressure. The residue was purified by silica gel column chromatography (eluent: hexane-AcOEt = 10 : 1) to give the benzoxepin (6b) (138 mg, 99%).