Platinum catalysed hydrolytic amidation of unactivated nitriles

Tetrahedron Letters

Volumn 41, Issue 14, 2000, Pages 2467-2470

  Cobley, Christopher J ^a   Van Den Heuvel, Marco ^a   Abbadi, Abdelilah ^a   De Vries, Johannes G ^a  

^a DSM RESEARCH   (Netherlands)

Author keywords

Amides; Homogeneous catalysis; Nitriles; Platinum compounds

Indexed keywords

NITRILE; PLATINUM COMPLEX; PYRROLIDINE DERIVATIVE;

AMIDATION; ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; REACTION ANALYSIS; STOICHIOMETRY;

EID: 0034175672     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(00)00181-7     Document Type: Article

References (22)

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2. For reviews of amide formation, see: (a) Beckwith, A. L. J.; Zabicky, J. In The Chemistry of Amides; Wiley: New York, 1970; p. 105; (b) Dopp, D.; Dopp, H. In Houben-Weyl, Methods of Organic Chemistry; Thieme: New York, 1985, p. 934.
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21. Observed by GC-MS analysis using a Cp sil 8 CB-MS, 30 m×0.25 mm Df=1.0 μm, injection temp.: 250°C, column temperature program: 5 min at 50°C (rate 7.5°C/min) 28 min at 250°C (rate 25°C/min) 30 min at 280°C, split: 1:50, flow: He 1.2 ml/min, injection volume: 1.0 μl.
22. All products are known compounds that show satisfactory GC-MS and NMR spectral data.