The molecular dynamics and reactivity of tris(inden-1-yl)silane: An NMR spectroscopic and X-ray crystallographic study

Journal of the Chemical Society. Perkin Transactions 2

Volumn , Issue 4, 2000, Pages 611-618

  Stradiotto, Mark ^a   Brook, Michael A ^a   McGlinchey, Michael J ^a  

^a MCMASTER UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; MOLECULAR DYNAMICS; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHASE TRANSITIONS; STEREOCHEMISTRY; STRUCTURE (COMPOSITION); SYNTHESIS (CHEMICAL); X RAY CRYSTALLOGRAPHY;

SIGMATROPIC SHIFTS; STRUCTURAL CHARACTERIZATION; TRISINDENYL SILANE; WILKINSONS CATALYSTS;

SILANES;

EID: 0034175174     PISSN: 03009580     EISSN: None     Source Type: Journal    
DOI: 10.1039/b000458h     Document Type: Article

References (35)

1. E. L. Muetterties, Inorg. Chem., 1965, 4, 769.
2. P. E. Rakita and A. Davison, Inorg. Chem., 1969, 8, 1164.
3. C. W. Spangler, Chem. Rev., 1976, 76, 187.
4. R. L. Halterman, Chem. Rev., 1992, 92, 965.
5. R. B. Woodward and R. Hoffmann, J. Am. Chem. Soc., 1965, 87, 2511.
6. R. B. Larrabee and B. F. Dowden, Tetrahedron Lett., 1970, 12, 915.
7. A. J. Ashe, III, Tetrahedron Lett., 1970, 24, 2105.
8. M. Stradiotto, S. S. Rigby, D. W. Hughes, M. A. Brook, A. D. Bain and M. J. McGlinchey, Organometallics, 1996, 15, 5645.
9. M. Stradiotto, P. Hazendonk, A. D. Bain, M. A. Brook and M. J. McGlinchey, Organometallics, 2000, 19, 590.
10. M. Stradiotto, D. W. Hughes, M. A. Brook, A. D. Bain and M. J. McGlinchey, Organometallics, 1997, 16, 5563.
11. M. Stradiotto, M. A. Brook and M. J. McGlinchey, Inorg. Chem. Commun., 1998, 1, 105.
12. A. Davison and P. E. Rakita, J. Organomet. Chem., 1970, 23, 407.
13. L. H. Sommer and N. S. Marans, J. Am. Chem. Soc., 1951, 73, 5135.
14. Y. Chen, M. D. Rausch and J. C. W. Chien, Organometallics, 1993, 12, 4607.
15. S. S. Rigby, L. Girard, A. D. Bain and M. J. McGlinchey, Organometallics, 1995, 14, 3798.
16. M. Stradiotto, M. A. Brook and M. J. McGlinchey, New J. Chem., 1999, 317.
17. A. D. McMaster and S. R. Stobart, J. Am. Chem. Soc., 1982, 104, 2109.
18. 3MR complexes only when the "R" fragment is either linear or possesses three-fold symmetry about the Si-R molecular axis.
19. J. L. Atwood, A. D. McMaster, R. D. Rogers and S. R. Stobart, Organometallics, 1984, 3, 1500.
20. B. Thiyagarajan, R. F. Jordan and V. G. Young, Organometallics, 1998, 17, 281.
21. G. Klebe, J. Organomet. Chem., 1985, 293, 147.
22. 3v symmetry.
23. R. Ruffolo, S. Kainz, H. K. Gupta, M. A. Brook and M. J. McGlinchey, J. Organomet. Chem., 1997, 547, 217.
24. R. J.P. Corriu, J. J. E. Moreau and H. Praet, Organometallics, 1989, 8, 2779.
25. C. L. Perrin and T. J. Dwyer, Chem. Rev., 1990, 90, 935.
26. M. Grassi, B. M. Mann, B. T. Pickup and C. M. Spencer, J. Magn. Reson., 1986, 69, 92.
27. J. J. Led and H. Gesmar, J. Magn. Reson., 1982, 49, 444.
28. D. R. Muhandiram and R. E. D. McClung, J. Magn. Reson., 1987, 71, 187.
29. A. D. Bain and J. A. Cramer, J. Magn. Reson., 1996, A 118, 21.
30. G. M. Sheldrick, SMART (1996), Release 4.05; Siemens Energy and Automation Inc., Madison, WI 53719.
31. G. M. Sheldrick, SAINT (1996) Release 4.05; Siemens Energy and Automation Inc., Madison, WI 53719.
32. G. M. Sheldrick, SADABS (Siemens Area Detector Absorption Corrections) (1996).
33. G. M. Sheldrick, Siemens SHELXTL (1994), Version 5.03; Siemens Crystallographic Research Systems, Madison, WI 53719.
34. R. N. Haszeldine, R. V. Parish and R. J. Taylor, J. Chem. Soc., Dalton Trans., 1974, 2311.
35. R. N. Haszeldine, R. V. Parish and D. J. Parry, J. Chem. Soc. (A). 1969, 683.