Improved synthesis of 1-adamantylphosphine and its use in the synthesis of cyclicphosphines containing 1-adamantyl group

Heterocycles

Volumn 52, Issue 2, 2000, Pages 905-910

  Ohashi, Atsushi ^a   Matsukawa, Satoru ^a   Imamoto, Tsuneo ^a  

^a CHIBA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ADAMANTANE DERIVATIVE; PHOSPHINE DERIVATIVE;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; SYNTHESIS;

EID: 0034143435     PISSN: 03855414     EISSN: None     Source Type: Journal    
DOI: 10.3987/com-99-s58     Document Type: Article

References (17)

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11. 4. The yield obtained by this procedure was 40% yield.
12. 4MgBr was also attempted for the synthesis of 1-adamantyldichlorophosphine. However, the yield of the product was very low (4% yield).
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15. 4. The solution was passed through a column of basic alumina using degassed ether. The eluent was evaporated in vacuo to leave practically pure desired phosphine ligands as colorless solid or oil.
16. -1; λ(Mo Kα) = 0.71069 Å; 27200 reflections measured; 3332 observed (I>1.50σ(I)); 405 variables; R = 0.048; Rw = 0.065; GOF = 1.05.
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