Use of a bench-top photochemical reactor and solid-phase microextraction to measure semivolatile organic compound-hydroxyl radical rate constants

Environmental Toxicology and Chemistry

Volumn 19, Issue 7, 2000, Pages 1705-1710

  Bernhard, Mary Jo ^a   Simonich, Staci L ^a  

^a PROCTER AND GAMBLE COMPANY   (United States)

Author keywords

Atmospheric half life; Hydroxyl radical; Semivolatile organic compounds; Solid phase microextraction

Indexed keywords

BIPHENYL; HYDROXYL RADICAL; LINALOOL; NAPHTHALENE; NITRITE; PHENANTHRENE; VOLATILE ORGANIC COMPOUND;

ATMOSPHERIC TRANSPORT; HYDROXYL RADICAL; MEASUREMENT METHOD; PHOTOCHEMISTRY;

ARTICLE; ATMOSPHERE; CHEMICAL REACTION KINETICS; HALF LIFE TIME; PHOTOCHEMISTRY; PRIORITY JOURNAL; REACTOR; SOLID PHASE EXTRACTION;

EID: 0034130863     PISSN: 07307268     EISSN: None     Source Type: Journal    
DOI: 10.1002/etc.5620190702     Document Type: Article

References (30)

1. Wania F, Mackay D. 1996. Tracking the distribution of persistent organic pollutants. Environ Sci Technol 30:390-396.
2. Simonich SL, Hites RA. 1995. Global distribution of persistent organochlorine compounds. Science 269:1851-1854.
3. Anderson PN, Hites RA. 1996. OH radical reactions: The major removal pathway for polychlorinated biphenyls from the atmosphere. Environ Sci Technol 30:1756-1763.
4. Commission for Environmental Cooperation. 1997. Process for identifying candidate substances for regional action under the sound management of chemicals initiative. Draft Report. Montreál, PQ, Canada.
5. European Economic Community. 1997. Working group on strategies: Report of the 21st session. Executive Body for the Convention on Long-range Transboundary Air Pollution. EB.AIR/ WG.5/44 3 July 1997. Brussels, Belgium.
6. Environment Canada. 1995. Toxic Substances Management Policy. Montréal, PQ, Canada.
7. Atkinson R, Aschmann SM. 1985. Rate constants for the gas-phase reaction of hydroxyl radicals with biphenyl and the monochlorobiphenyls at 295 ± 1 K. Environ Sci Technol 19:462-464.
8. Kwok ESC, Harger WP, Arey J, Atkinson R. 1994. Reactions of gas-phase phenanthrene under simulated atmospheric conditions. Environ Sci Technol 28:521-527.
9. Biermann HW, Mac Leod H, Atkinson R, Winer AM, Pitts JN. 1985. Kinetics of the gas-phase reactions of the hydroxyl radical with naphthalene, phenanthrene, and anthracene. Environ Sci Technol 19:244-248.
10. 3 at 294 ± 1 K. Environ Sci Technol 18:110-113.
11. 3 at 295 ± 1 K. Int J Chem Kinet 18:569-573.
12. 3 reactions. Int J Chem Kinet 27:941-955.
13. Anderson PN, Hites RA. 1996. System to measure relative rate constants of semivolatile organic compounds with hydroxyl radicals. Environ Sci Technol 30:301-306.
14. Brubaker WW, Hites RA. 1997. Polychlorinated dibenzo-p-dioxins and dibenzofurans: Gas-phase hydroxyl radical reactions and related atmospheric removal. Environ Sci Technol 31:1805-1810.
15. Shi J, Bernhard MJ. 1997. Kinetic studies of Cl-atom reactions with selected aromatic compounds using the photochemical reactor-FTIR spectroscopy technique. Int J Chem Kinet 29:349-358.
16. 3 radicals, UV absorption cross sections, and vapor pressures. Environ Sci Technol 31:3166-3172.
17. Glasius M, Calogirou A, Jensen NR, Hjorth J, Nielsen CJ. 1997. Kinetic study of gas-phase reactions of pinonaldehyde and structurally related compounds. Int J Chem Kinet 29:527-533.
18. Atkinson R, Tuazon EC, Aschmann SM. 1995. Products of the gas-phase reactions of a series of 1-alkenes and 1-methylcyclohexene with the OH radical in the presence of NO. Environ Sci Technol 29:1674-1680.
19. Maeno S, Rodriguez PA. 1996. Simple and versatile injection system for capillary gas chromatographic columns - Performance evaluation of a system including mass spectrometric and light pipe Fourier-transform infrared detection. J Chromatogr 731: 201-215.
20. Atkinson R, Aschmann SM, Carter WPL, Winer AM, Pitts JN. 1982. Kinetics of the reactions of OH radicals with normal-alkanes at 299 ± 2 K. Int J Chem Kinet 14:781-788.
21. Atkinson R. 1989. Gas phase tropospheric chemistry or organic compounds. J Phys Chem Ref Data Monogr 1:1-246.
22. 3 at 296 ± 2 K. Int J Chem Kinet 20:513-539.
23. Bignozzi CA, Maldotti A, Chiorboli C, Bartocci C, Carassiti V. 1981. Kinetics and mechanism of reactions between aromatic olefins and hydroxyl radicals. Int J Chem Kinet 13:1235-1242.
24. Meylan WM, Howard PH. 1993. Computer estimation of the atmospheric gas-phase reaction-rate of organic-compounds with hydroxyl radicals and ozone. Chemosphere 26:2293-2299.
25. Syracuse Research Corporation. 1995. Users Guide for AOPWIN. Syracuse, NY, USA.
26. Kwok ESC, Atkinson RA. 1995. Estimation of hydroxyl radical reaction rate constants for gas-phase organic compounds using a structure-reactivity relationship: An update. Atmos Environ 29: 1685-95.
27. 3. Environ Sci Technol 31:896-904.
28. Moder M, Popp P, Pawliszyn J. 1998. Characterization of water-soluble components of slurries using solid-phase microextraction coupled to liquid chromatography-mass spectrometry. J Microcolumn Sep 10:225-234.
29. 3 and global OH concentrations. Science 269: 187-192.
30. Mackay D, Shiu WY, Ma KC. 1992. Illustrated Handbook of Physical-Chemical Properties and Environmental Fate of Organic Chemicals. Lewis, Chelsea, MI, USA.