Catalytic decomposition of ethanol on V2O5/AlPO4 catalysts

Journal of Chemical Technology and Biotechnology

Volumn 75, Issue 3, 2000, Pages 196-204

  Said, Abd El Aziz A ^a   Khalil, Kamal M S ^b  

^a Assiut University   (Egypt)

^b SOHAG UNIVERSITY   (Egypt)

Author keywords

Aluminum phosphate; Decomposition of ethanol; Supported catalysts; Vanadium pentoxide

Indexed keywords

ADSORPTION; ALUMINUM COMPOUNDS; CALCINATION; CATALYST SELECTIVITY; DECOMPOSITION; DIFFERENTIAL SCANNING CALORIMETRY; ELECTRIC CONDUCTIVITY; ETHANOL; IMPREGNATION; PHOSPHATES; THERMOGRAVIMETRIC ANALYSIS; VANADIUM COMPOUNDS;

ALUMINUM PHOSPHATE; CATALYTIC DECOMPOSITION; VANADIUM PENTOXIDE;

CATALYST ACTIVITY;

ALCOHOL; ALUMINUM PHOSPHATE; VANADIUM PENTOXIDE;

ARTICLE; CATALYSIS; CATALYST; DECOMPOSITION;

EID: 0034104573     PISSN: 02682575     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1097-4660(200003)75:3<196::AID-JCTB193>3.0.CO;2-J     Document Type: Article

References (30)

1. Bozik JE, Vogel RF, Kissin YV and Beach DL, Metallophosphate-supported Zeigler-natta catalysts for ethylene polymerization. J Appl Polym Sci., 29:3491-3497 (1984).
2. McDaniel MB, Advances in Catalysis Vol 33, Academic Press, New York. p 47 (1986).
3. Marcelin G, Vogel RF and Swift HE, Alumina-aluminum phosphate as a large-pore support and its application to liquid phase hydrogenation. J Catal 83:42-49 (1983).
4. 2) catalysts prepared by a sol-gel procedure. J Catal 179:483-494 (1998).
5. Hucknall DJ, Selective Oxidation of Hydrocarbons, Academic Press, London (1974).
6. Gellings PJ, Catalysis, Vol 7, Royal Society of Chemistry, London, p 105 (1985).
7. Bond GC and Flamerz S, Structure and reactivity of titania-supported oxide, IV. Characterization of dried vanadia/titania catalysts. Appl Catal 46:89-102 (1989).
8. 5 in vanadia-silica catalysts. J Catal 118:22-30 (1989).
9. Catal Today 16:1-8 (1993), Proceedings, Vanadyl Pyrophosphate Catalysts (Centi , G. Ed).
10. Guliants VV, Benziger JB, Sundaresan S, Yao N and Wachs IE, Evolution of the active surface of the vanadyl pyrophosphate catalysts. Catal Lett 32:379-386 (1995).
11. 2 precursor for n-butane oxidation into maleic anhydride. J Catal 154:253-260 (1995).
12. 2O. J Solid State Chem 63:202-215 (1986).
13. Smith JV (Ed), X-Ray Powder Data File, American Soc for Testing Materials, Philadelphia (1960).
14. Said AA, Hassan EA and Abd El-Salaam KM, Electrical conductivity and thermogravimetric studies of the thermal decomposition of cobalt carbonate. Surf Technol 20:123-130 (1983).
15. 3 support on the thermal decomposition of ammonium metavanadate. J Mat Sci 27:5869-5872 (1992).
16. 4 catalysts. J Catal 151:307-314 (1995).
17. Davis ME, Monte C, Hathaway PE, Arhancet JP, Hasha DL and Garces JM, Physicochemical properties of VPI-5. J Am Chem Soc 111:3919-3924 (1989).
18. 2 groups and encapsulated water. Acta Crystallog Sect C Cryst Struct Commun 9:1118-1120 (1986).
19. Frederickson LD and Hausen DM, Infrared spectra-structure correlation study of V-O compounds. Anal Chem 35:818-827 (163).
20. Ben Abdelouahab F, Olier R, Guilhaume N, Lefebvre F and Volta JC, A study by in situ laser raman spectroscopy of VPO catalysts for a-butane oxidation to maleic anhydride. J Catal 134:151-167 (1992).
21. Yamaguchi O, Formation of AlVO4 (aluminum vanadate) solid solution from alkoxide. J Am Ceram Soc 70:198-200 (1987).
22. Brunauer S, Deming LS, Deming WS and Teller E, A theory of the Van der Waals adsorption of gases. J Am Chem Soc 62:1723-1732 (1940).
23. Herrmann JM, Vernoux P, Bere KE and Abon M, In situ study of redox and of p-type semiconducting properties of vanadyl pyrophosphate and of V-P.O catalysts during the partial oxidation of n-butane to maleic anhydride. J Catal 167:106-117 (1997).
24. Morrison SR, In Chemical Physics of Surfaces, Plenum, New York. p 70 (1977).
25. 4 catalysts. Can J 61:2567-2571 (1983).
26. Flanigen EM, Patton RL and Wilson ST, Structural, synthetic and physicochemical concepts in aluminophosphate-based molecular sieves. Stud Surf Sci Catal 37:13-27 (1988).
27. Hodnett BK, Vanadium-Phosphorus oxide catalysts for the selective oxidation of C4 hydrocarbons to maleic anhydride. Catal Rev Sci Eng 37:373-424 (1985).
28. Abdel-Wahab MMM and Said AA, Influence of the formation of aluminum spinel, A1VO4, on the catalytic activity of V2O5 support on γ-alumina. Collect Czech Chem Commun 59:1983-1990 (1994).
29. Greenwood NN, Ionic Crystals Lattice Defects and Non-Stoichiometry, Butterworth, London, p 40 (1968).
30. Kröger FA. Chemistry of Imperfect Crystals, North Holland, Amsterdam (1964).