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European Journal of Inorganic Chemistry

Volumn , Issue 6, 2000, Pages 1147-1150

The first Ru(II) bipyridyl-capped cyclodextrin: Evidence of electron- transfer through the cavity

(3) Armspach, Dominique a Matt, Dominique a Harriman, Anthony b

a UNIVERSITÉ DE STRASBOURG (France)

b NEWCASTLE UNIVERSITY (United Kingdom)

Author keywords

Cyclodextrins; Electron transfer; Inclusion compounds; N ligands; Ruthenium

Indexed keywords

ELECTRON TRANSITIONS; RUTHENIUM COMPOUNDS;

BENZOQUINONES; BIPYRIDYL; DIASTEREOMERIC; ELECTRON TRANSFER; INCLUSION COMPOUNDS; N LIGANDS; N-LIGANDS; STEADY STATE; TIME-RESOLVED EMISSIONS; Α-CYCLODEXTRINS;

CYCLODEXTRINS;

BIPYRIDINE; CYCLODEXTRIN;

ARTICLE; BINDING AFFINITY; DIASTEREOISOMER; ELECTRON TRANSPORT; NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; STEADY STATE;

EID: 0034088592 PISSN: 14341948 EISSN: None Source Type: Journal
DOI: 10.1002/(SICI)1099-0682(200006)2000:6<1147::AID-EJIC1147>3.3.CO;2-U Document Type: Article

Times cited : (26)

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- Molecule 4 combines an enantiomerically pure cyclodextrin fragment with the dissymetric ruthenium centre. This combination results in the formation of two diastereomers.

9
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- a values, namely H-3,3′ protons of the 4,4′-dicarbonyl-2,2′-bipyridyl moiety and one of the CD MeO-3 signals.

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11
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- -1).

12
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- 2 axis. The estimated edge-to-edge separation stands for the distance between an N atom of the substituted bipy and the nearest BQ-oxygen atom.

13
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- Numbering in α-CD: (matrix presented)
- Numbering in α-CD: (matrix presented)

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