Intramolecular 6-exo cyclization of 1-nitro-6-heptenyl radicals generated by one-electron oxidation of aci-nitroanions with CAN: A completely stereoselective formation of 2,3,4-trisubstitated tetrahydropyrans

Synlett

Volumn , Issue 5, 2000, Pages 731-733

  Durand, Anne Catherine ^a   Rodriguez, Jean ^a   Dulcère, Jean Pierre ^a  

^a AIX MARSEILLE UNIVERSITY   (France)

Author keywords

nitro alkenyl radicals; 2,3,4 trisubstituted tetrahydropyrans; CAN; Stereoselective radical cyclization

Indexed keywords

ACETIC ACID DERIVATIVE; NITRO DERIVATIVE; TETRAHYDROPYRAN DERIVATIVE;

ARTICLE; CHEMICAL BINDING; CYCLIZATION; OXIDATION; REACTION ANALYSIS; STEREOCHEMISTRY; SYNTHESIS;

EID: 0034074361     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (51)

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38. Assignments of stereochemistries for 6a-d were deduced from NOESY experiments.
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