Discrimination and thermal degradation of toxaphene compounds in capillary gas chromatography when using split/splitless and on-column injection

Chemosphere

Volumn 41, Issue 4, 2000, Pages 473-479

  Buser, Hans Rudolf ^a   Haglund, Peter ^b   Müller, Markus D ^a   Poiger, Thomas ^a   Rappe, Christoffer ^b  

^a Swiss Federal Research Station for Fruit Growing Viticulture and Horticulture   (Switzerland)

^b UMEÅ UNIVERSITY   (Sweden)

Author keywords

Chlorobornanes; Chlorocamphenes; Injection techniques; Thermal degradation; Toxaphene analysis

Indexed keywords

BORNANE DERIVATIVE; CAMPHECLOR;

ARTICLE; CAPILLARY GAS CHROMATOGRAPHY; CHEMICAL ANALYSIS; DEGRADATION; ELECTRON CAPTURE DETECTION; MASS SPECTROMETRY;

BORANES; BORNANES; CHLORINE COMPOUNDS; CHROMATOGRAPHY, GAS; INSECTICIDES; TEMPERATURE; TOXAPHENE;

EID: 0034056717     PISSN: 00456535     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0045-6535(99)00481-6     Document Type: Article

References (20)

1. Alder L., Vieth B. A congener-specific method for the quantification of camphechlor (toxaphene) residues in fish and other foodstuffs. Fresenius' J. Anal. Chem. 354:1996;81-92.
2. Baycan-Keller R., Oehme M. Thermal decomposition of toxaphene congeners by high resolution gas chromatographic phases. J. High Resol. Chromatogr. 21:1998;298-302.
3. Bidleman T.F., Walla M.D., Muir D.C.G., Stern G.A. Selective accumulation of polychloro-camphenes in aquatic biota from the Canadian arctic. Environ. Toxicol. Chem. 12:1993;701-709.
4. Buser, H.R., Haglund, P., Müller, M.D., Poiger, T., Rappe, C., 2000. Rapid anaerobic degradation of toxaphene in sewage sludge, Chemosphere 40, 1213-1220.
5. Buser H.R., Müller M.D. Isomer- and enantiomer-selective analyses of toxaphene components using chiral high-resolution gas chromatography and detection by mass spectrometry mass spectrometry. Environ. Sci. Technol. 28:1994;119-128.
6. de Gaus H.J., Besselink H., Brouwer A., Klungsoyr J., MacGovern E., MacHugh B., Nixon E., Rimkus G.G., Wester P.G., de Boer J. Developments in analysis and toxicology of toxaphene compounds. Organohalogen Compd. 35:1998;217-220.
7. Grob, k., 1979. Evaluation of injection techniques for triglycerides in capillary gas chromatography. J. Chromatogr. 178, 387-392.
8. Grob, K., 1986. Classical split and splitless injection in capillary GC. Hüthig, Heidelberg.
9. Grob, K., 1991. On-column injection in capillary gas chromatography, basic technique, retention gaps, solvent effect, second ed. Hüthig, Heidelberg.
10. 10-chloroterpenes from a photochemically modified toxaphene standard. Fresenius' J. Anal. Chem. 351:1995;271-285.
11. Lau B., Weber D., Andrews P. GC/MS analysis of toxaphene: a comparative study of different mass spectrometric techniques. Chemosphere. 32:1996;1021-1041.
12. Muir, D.C.G., Grift, N.P., Ford, C.A., Reiger, A., Hendzel, M., Lockhart, W.L., 1990. In: Long Range Transport of Pesticides, Kurtz, D. (Ed.), Lewis Publishers, Chelsea, MI, pp. 329-346.
13. Musial C.J., Uthe J.F. Wide-spread occurrence of the pesticide toxaphene in Canadian east coast marine fish. Int. J. Environ. Anal. Chem. 14:1983;117-124.
14. Parlar H., Angerhöfer D., Coelhan M., Kimmel L. HRGC and HRGC-ECNI determination of toxaphene residues in fish with a new 22 components standard. Organohalogen Compd. 26:1995;357-362.
15. Saleh M.A. Toxaphene: chemistry, biochemistry, toxicity and environmental fate. Rev. Environ. Contam. Toxicol. 118:1991;1-66.
16. Schomburg G., Husmann H., Rittmann R. Direct (on-column) sampling into glass capillary columns, comparative investigations on split, splitless and on-column sampling. J. Chromatogr. 204:1981;85.
17. Sittig, M., 1980. Pesticide manufacturing and toxic materials encyclopedia, Noyes Data, Park Ridge, NJ, p. 734.
18. Stern G.A., Loewen M.D., Miskimmin B.M., Muir D.C.G., Westmore J.B. Characterization of two toxaphene components in treated lake sediment. Environ. Sci. Technol. 30:1996;2251-2258.
19. Swackhamer D.L., Charles M.J., Hites R.A. Quantitation of toxaphene in environmental samples using negative ion chemical ionization mass spectrometry. Anal. Chem. 59:1987;913-917.
20. Xu L., Hainzl D., Burhenne J., Parlar H. HRGC-ECD and HRGC-NICI SIM quantification of toxaphene residues in selected marine organisms by environmentally relevant chlorobornanes as standards. Chemosphere. 28:1994;237-243.