Single-crystal IR- and UV/VIS-spectroscopic measurements on transition-metal-bearing pyrope: The incorporation of hydroxide in garnet

European Journal of Mineralogy

Volumn 12, Issue 2, 2000, Pages 259-271

  Geiger, Charles A ^a   Stahl, Andreas ^a   Rossman, George R ^b  

^a UNIVERSITY OF KIEL   (Germany)

^b CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

Grospydites; Hydrogarnet substitution; OH groups; Pyrope; Transition metal ions; UV VIS and IR absorption spectroscopy

Indexed keywords

ABSORPTION SPECTROSCOPY; GARNETS; LIGHT ABSORPTION; METAL IONS; SINGLE CRYSTALS; TITANIUM; TRANSITION METALS;

GROSPYDITES; HYDROGARNET; IR ABSORPTION SPECTROSCOPY; OH^--GROUPS; PYROPE;

TRANSITION METAL COMPOUNDS;

CRYSTAL CHEMISTRY; GARNET; HYDROXIDE; PYROPE;

EID: 0034049392     PISSN: 09351221     EISSN: None     Source Type: Journal    
DOI: 10.1127/0935-1221/2000/0012-0259     Document Type: Article

References (32)

1. Ackermann, L., Cemič, L., Langer, K. (1983): Hydrogarnet substitution in pyrope: a possible location for "water" in the mantle. Earth Planet. Sci. Lett., 62, 208-214.
2. Aines, R.D. & Rossman, G.R. (1984): Water content of mantle garnets. Geology, 12, 720-723.
3. Amthauer, G. (1976): Kristallchemie und Farbe chromhaltiger Granate. N. Jb. Mineral. Abh., 126, 158-186.
4. Armbruster, T., Birrer, J., Libowitzky, E., Beran, A. (1998): Crystal-chemistry of Ti-bearing andradites. Eur. J. Mineral., 10, 907-921.
5. Basso, R., Cimmino, F., Messiga, B. (1984): Crystal chemistry of hydrogarnets from three different microstructural sites of a basaltic metarodingite from the Voltri Massif (Western Liguria, Italy). N. Jb. Mineral. Abh., 148, 246-258.
6. Bell, D.R. & Rossman, G.R. (1992a): The hydrous component in garnets from the subcontinental mantle of southern Africa. Contrib. Mineral. Petrol., 111, 161-178.
7. _, _ (1992b): Water in Earth's mantle: the role of nominally anhydrous minerals. Science, 255, 1391-1397.
8. Beran, A., Langer, K., Andrut, M. (1993): Single crystal infrared spectra in the range of OH fundamentals of paragenetic garnet, omphacite and kyanite in an eclogitic mantle xenolith. Mineral. Petrol., 48, 257-268.
9. Burns, R.G. (1993): Mineralogical Applications of Crystal Field Theory, 2. edition. Putnis ed., Cambridge, 551 p.
10. Cemič, L., Geiger, C.A., Hoyer, W.W., Koch-Müller, M., Langer, K. (1990): Piston-cylinder techniques: Pressure and temperature calibration of a pyrophyllite-based assembly by means of DTA measurements, a salt-based assembly, and a cold sealing sample encapsulation method. N. Jb. Mineral. Mh., 1990/2, 49-64.
11. Cho, H. & Rossman, G.R. (1993): Single-crystal NMR studies of low-concentration hydrous species in minerals: Grossular garnet. Am. Mineral., 78, 1149-1164.
12. 3.36 de type grenat. Acta Cryst., 23, 220-230.
13. Geiger, C.A., Lager, G.A., Amthauer, G., Richardson, J.K, Armbruster, T. (1989): Almandine garnet: synthesis, structure, and Mössbauer and NIR spectroscopy. XII European Crystallographic Meeting, Moscow, USSR, Collected Abstracts, 2, 6.
14. Geiger, C.A., Langer, K., Bell, D.R., Rossman, G.R., Winkler, B. (1991): The hydroxide component in synthetic pyrope. Am. Mineral., 76, 49-59.
15. 4- cluster in hydrogrossular. J. Mol. Structure, 82, 213-219.
16. Ihinger, P.D. & Stolper, E. (1986): The color of meteoritic hibonite: an indicator of oxygen fugacity. Earth Planet. Sci. Lett., 78, 67-79.
17. Khomenko, V.M., Langer, K., Beran, A., Koch-Müller, M., Fehr, T. (1994a): Titanium substitution and OH-bearing defects in hydrothermally grown pyrope crystals. Phys. Chem. Minerals, 20, 483-488.
18. Khomenko, V.M., Langer, K., Andrut, M., KochMüller, M., Vishnevsky, A.A. (1994b): Single crystal absorption spectra of synthetic Ti, Fe-substituted pyropes. Phys. Chem. Minerals., 21, 434-440.
19. Lager, G.A., Armbruster, T., Rotella, F.J., Rossman, G.R. (1989): OH-substitution in garnets: X-ray and neutron diffraction, infrared, and geometricmodeling studies. Am. Mineral., 74, 840-851.
20. Mackwell, S.J. & Kohlstedt, D.L. (1990): Diffusion of hydrogen in olivine: implications for water in the mantle. J. Geophys. Res., 95, 5079-5088.
21. Manning, P.G. & Harris, D.C. (1970): Optical-absorption and electron-microprobe studies of some high-Ti andradites. Can. Mineral., 10, 260-271.
22. Martin, R.F. & Donnay, G. (1972): Hydroxyl in the mantle. Am. Mineral., 57, 554-570.
23. Matsyuk, S.S., Langer, K., Hösch, A. (1998): Hydroxyl defects in garnets from mantle xenoliths in kimberlites of the Siberian platform. Contrib. Mineral. Petrol., 132, 163-179.
24. Reid, A.M., Brown, R.W., Dawson, J.B., Whithefield, G.G. (1976): Garnet and pyroxene compositions in some diamondiferous eclogites. Contrib. Mineral. Petrol., 58, 203-220.
25. 3 garnet. Am. Mineral., 81, 61-66.
26. Rossman, G.R. & Aines, R.D. (1991): The hydrous components in garnets: Grossular-hydrogrossular. Am. Mineral., 76, 1153-1164.
27. Rossman, G.R., Beran, A., Langer, K. (1989): The hydrous component of pyrope from the Dora Maira Massif, Western Alps. Eur. J. Mineral., 1, 151-154.
28. Schmetzer, K. & Ottemann, J. (1979): Kristallchemie und Farbe Vanadium-haltiger Granate. N. Jb. Mineral. Abh., 136, 146-168.
29. Tanabe, Y. & Sugano, S. (1954): On the absorption spectra of complex ions I, II. J. Phys. Soc. Japan, 9, 753-779.
30. Weber, M.J. & Riseberg, L.A. (1971): Optical spectra of vanadium ions in yttrium aluminum garnet. J. Chem. Phys., 55, 2032-2038.
31. Wilkins, R.W.T. & Sabine, W. (1973): Water content of some nominally anhydrous silicates. Am. Mineral., 58, 508-516.
32. Withers, A.C., Wood, B.J., Carroll, M.R. (1998): The OH content of pyrope at high pressure. Chemical Geol., 147, 161-171.