A practical synthetic method for α- and β-glycosyloxyacetic acids

Heterocycles

Volumn 52, Issue 1, 2000, Pages 129-132

  Mandai, Tadakatsu ^a   Okumoto, Hiroshi ^a   Oshitari, Tetsuta ^a   Nakanishi, Katsuyoshi ^b   Mikuni, Katsuhiko ^b   Hara, Ko Ji ^b   Hara, Ko Zo ^b  

^a KURASHIKI UNIVERSITY OF SCIENCE AND THE ARTS   (Japan)

^b Bio Research Corporation of Yokohama   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYL 2,3,4 TRI O BENZYL 6 O TRITYLGLYCOSIDE; ALPHA GLYCOSYLOXYACETIC ACID; BETA GLYCOSYLOXYACETIC ACID; GLYCOLIC ACID DERIVATIVE; TAXOL DERIVATIVE; TRITYL DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; COLUMN CHROMATOGRAPHY; DRUG PURIFICATION; DRUG SYNTHESIS; HYDROXYLATION; OXIDATION; SOLUBILITY; STRUCTURE ACTIVITY RELATION;

EID: 0033978519     PISSN: 03855414     EISSN: None     Source Type: Journal    
DOI: 10.3987/COM-99-S43     Document Type: Article

References (6)

1. ® Science and Applications, ed. by M. Suffness, CRC:Boca Raton, FL, 1995.
2. E. A. Talley, M. D. Vale, and E. Yanovsky, J. Am. Chem. Soc., 1945, 67, 2037 and references cited therein.
3. (a) M. A. Caller and P. M. Sugathapala, Tetrahedron Lett., 1998, 39, 8813.
4. (b) For review: R. H. DeWolfe, Synthesis, 1974, 153. cf: The author in the literature (a) prepared triallyl orthoformate and cited literature (b). However, none of the yield and synthetic procedure was described anywhere.
5. 3 powder. After the volatile components having been distilled under an atmospheric pressure, the residue was distilled invacuo (90-100 °C/ca. 20 mmHg) to give 38-45% of triallyl orthoformate with the satisfactory purity for usual synthetic use.
6. 2), 6.86 (2H, aromatic), 7.16-7.40 (28H, aromatic).