Mechanistic study of trivalent europium transport through supported liquid membranes (SLMs) and a novel immobilized phase solvent extraction (IPSE) system

Journal of Membrane Science

Volumn 165, Issue 2, 2000, Pages 273-291

  Boerrigter, Harold ^a   Tomasberger, Tanja ^a   Booij, Arend S ^a   Verboom, Willem ^b   Reinhoudt, David N ^b   De Jong, Feike ^b  

^a NUCLEAR RESEARCH AND CONSULTANCY GROUP NRG   (Netherlands)

^b UNIVERSITY OF TWENTE   (Netherlands)

Author keywords

Cavitand based carriers; Diffusion processes; Extraction of cations; Nuclear waste separations

Indexed keywords

DIFFUSION IN LIQUIDS; EUROPIUM; NITRATES; RADIOACTIVE TRACERS; RADIOACTIVE WASTE VITRIFICATION; SOLVENT EXTRACTION;

IMMOBILIZED PHASE SOLVENT EXTRACTION (IPSE); SUPPORTED LIQUID MEMBRANES (SLM);

LIQUID MEMBRANES;

CATION; EUROPIUM; SOLVENT;

EXTRACTION; LIQUID MEMBRANE; TRANSPORT;

ARTICLE; DIFFUSION; EXTRACTION; LIQUID MEMBRANE; MEMBRANE TRANSPORT; NUCLEAR WASTE; PRIORITY JOURNAL;

EID: 0033976937     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0376-7388(99)00237-9     Document Type: Article

References (38)

1. H.A.C. McKay, J.H. Miles, J.L. Swanson, Science and technology of tributyl phosphate, in: W.W. Schulz, J.D. Navratil (Eds.), CRC Press, Boca Raton, 1984, p. 1.
2. E.P. Horwitz, W.W. Schulz, New separation chemistry, techniques for radioactive waste and other specific applications, in: E.P. Horwitz, W.W. Schulz (Eds.), Applied Science, Elsevier, New York, 1991, p. 21.
3. C. Madic, P. Blanc, N. Condamines, P. Baron, L. Berthon, C. Nicol, C. Pozo, M. Lecompte, M. Philippe, M. Masson, C. Hequet, M.J. Hudson, Actinide partitioning from high level liquid waste using DIAMEX process, Proc. RECOd’94, London (England), 1994.
4. G.Y.S. Chan, M.G.B. Drew, M.J. Hudson, P.B. Iveson, J.-O. Liljenzin, M. Skålberg, L. Spjuth, C. Madic, Solvent extraction of metal ions from nitric acid solution using N,N′-substituted malonamides. Experimental and crystallographic evidence for two mechanisms of extraction, metal complexation and ion-pair formation, J. Chem. Soc., Dalton Trans. (1997) 649.
5. Chen J., Jiao R., Zhu Y. A cross-flow hot test for separating Am from fission product lanthanides by bis(2,4,4-trimethylpentyldithiophosphinic acid extraction. Radiochim. Acta. 76:1997;129.
6. H.C. Visser, D.N. Reinhoudt, F. De Jong, Carrier-mediated transport through liquid membranes, Chem. Soc. Rev. (1994) 75.
7. Danesi P.R. Separation of metal species by supported liquid membranes. Sep. Sci. Tech. 19:1984-1985;857.
8. Neplenbroek A.M., Bargeman D., Smolders C.A. Supported liquid membranes: instability effects. J. Membr. Sci. 67:1992;121.
9. Dozol J.F., Casas J., Sastre A. Stability of flat sheet supported liquid membranes in the transport of radionuclides from reprocessing concentrate solutions. J. Membr. Sci. 82:1993;237.
10. Danesi P.R., Chiarizia R., Rickert P., Horwitz E.P. Separation of actinides and lanthanides from acidic nuclear wastes by supported liquid membranes. Solv. Ex. Ion Exch. 3:1985;111.
11. Chiarizia R., Danesi P.R. A double liquid membrane system for the removal of actinides and lanthanides from acidic nuclear wastes. Sep. Sci. Tech. 22:1987;641.
12. Nakamura S., Akiba K. Transport of europium through supported liquid membrane containing dihexyl-N,N-diethylcarbamoylmethylphosphonate. Sep. Sci. Tech. 24:1989;1317.
13. Arnaud-Neu F., Böhmer V., Dozol J.-F., Grüttner G., Jakobi R.A., Kraft D., Mauprivez O., Rouquette H., Schwing-Weill M.-J., Simin N., Vogt W. Calixarenes with diphenylphosphoryl acetamide functions at the upper rim. A new class of highly efficient extractants for lanthanides and actinides. J. Chem. Soc., Perkin Trans. 2:1996;1175.
14. Th. Ngo Manh, R. Kopunec, Carrier-mediated transport of rare earth elements through liquid membranes transport of Sc, Y, Ce, Eu, Gd, Tm, Yb through supported liquid membrane containing TOPO in n-dodecane, J. Radioan. Nucl. Chem., Articles 159 (1992) 219 and earlier papers.
15. G.R. Choppin, E.N. Rizkalla, in: K.A. Gschneider, Jr., L. Eyring, G.R. Choppin, G.H. Lander (Eds.), Handbook of the Physics and Chemistry of Rare Earths, vol. 18, Elsevier, Amsterdam, 1994, p. 559.
16. 3+ through a bis(2-ethylhexyl)phosphoric acid, n-dodecane solid supported liquid membrane. Sep. Sci. Tech. 17:1982;1183.
17. Danesi P.R., Horwitz E.P., Rickert P.G. Rate and mechanism of facilitated americium(III) transport through a supported liquid membrane containing a bifunctional organophosphorus mobile carrier. J. Phys. Chem. 87:1983;4708.
18. Dozol J.F., Casas J., Sastre A.M. Influence of the extractant on strontium transport from reprocessing concentrate solutions through flat-sheet supported liquid membranes. Sep. Sci. Tech. 29:1994;1999.
19. L.A.J. Chrisstoffels, F. De Jong, D.N. Reinhoudt, Mechanistic studies of carrier-mediated transport through supported liquid membranes in: R.A. Bartsch, J. Douglas Way (Eds.), Chemical Separations with Liquid Membranes, ACS Symp. Ser. 642, Am. Chem. Soc., Anaheim, CA, 1996, pp. 18-56.
20. Boerrigter H., Grave L., Nissink J.W.M., Chrisstoffels L.A.J., Van der Maas J.H., Verboom W., De Jong F., Reinhoudt D.N. (Thio)urea resorcinarene cavitands. Complexation and membrane transport of halide anions. J. Org. Chem. 63:1998;4174.
21. Casnati A., Pochini A., Ungaro R., Ugozzoli F., Arnaud F., Fanni S., Egberink M.R.J.M., De Jong F., Reinhoudt D.N., Schwing M.-J. Synthesis, complexation, and membrane transport studies of 1,3-alternate calix[4]arene-crown-6 conformers: a new class of cesium selective ionophores. J. Am. Chem. Soc. 117:1995;2767.
22. Boerrigter H., Verboom W., Reinhoudt D.N. Novel resorcinarene cavitand-based CMP(O) cation ligands: synthesis and extraction properties. J. Org. Chem. 62:1997;7148.
23. H. Boerrigter, T. Tomasberger, W. Verboom, D.N. Reinhoudt, Novel ligands for the separation of trivalent lanthanides and actinides. Tetrakis(phosphane sulfide) and -(phosphinic acid) cavitands, Eur. J. Org. Chem. (1999) 665.
24. A. Kemperman, Stabilization of supported liquid membranes, Thesis University of Twente, Enschede, The Netherlands, 1995.
25. Shinho T., Yamaguhi T., Yanagishita H., Sakaki K., Kitamoto D., Sugiura M. Supported liquid membranes for enantioselective transport of amino acid mediated by chiral crown ether - effect of membrane solvent on transport rate and membrane stability. J. Membr. Sci. 84:1993;241.
26. H.C. Visser, Supported liquid membranes with improved stability; kinetics and mechanism of carrier mediated salt transport, Thesis University of Twente, Enschede, The Netherlands, 1994.
27. Boerrigter H., Verboom W., De Jong F., Reinhoudt D.N. Europium(III) extraction with resorcinarene cavitand CMP(O) ligands: solvent extraction and mechanistic study. Radiochim. Acta. 81:1998;39.
28. Brooks B.R., Bruccoleri R.E., Olafsen B.D., States D.J., Swaminathan S., Karplus M. CHARMM: a program for macromolecular energy minimization and dynamics calculations. J. Comput. Chem. 4:1983;187.
29. Wilke C.R., Chang P. Correlation of diffusion coefficients in dilute solutions. AIChE J. 1:1955;264.
30. Huang T.-C., Juang R.-S. Transport of zinc through a supported liquid membrane using di(2-ethylhexyl) phosphoric acid as a mobile carrier. J. Membr. Sci. 31:1987;209.
31. Van den Berg R., Schulze D., Bolt-Westerhof J.A., De Jong F., Reinhoudt D.N., Velinova D., Buitenhuis L. Influence of membrane microstructure on the diffusion barrier of supported liquid crystalline membranes. J. Phys. Chem. 99:1995;7760.
32. II based on CMPO-functionalized resorcinarene cavitands; synthesis and extraction, Liebigs Ann./Recueil (1997) 2247.
33. Danesi P.R., Cianetti C. Permeation of metal ions through a series of two complementary supported liquid membranes. J. Membr. Sci. 20:1984;201.
34. Danesi P.R., Cianetti C. Multistage separation of metal ions with a series of composite supported liquid membranes. J. Membr. Sci. 20:1984;215.
35. Szpakowska M., Nagy O.B. Non-steady state versus steady state kinetic analysis of coupled ion transport through binary liquid membranes. J. Membr. Sci. 76:1993;27.
36. Y. Marcus, A.S. Kertes, Ion Exchange and Solvent Extraction of Metal Complexes, Wiley-Interscience, London, 1969, pp. 921-926.
37. CRC Handbook of Chemistry and Physics, in: D.R. Lide, H.P.R. Frederikse (Eds.), 75th edn., Boca Raton, CRC Press, 1995, p. 8-64.
38. Horwitz E.P., Muscatello A.C., Kalina D.G., Kaplan L. The extraction of selected transplutonium(III) and lanthanide(III) ions by dihexyl-N,N-diethylcarbamoylmethylphosphonate from aqueous nitrate media. Sep. Sci. Tech. 16:1981;417.