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For a very recent application see: S. Y. Lai, T. W. Lin, Y. H. Chen, C. C. Wang, G. H. Lee, M. H. Yang, M. K. Leung, S. M. Peng, J. Am. Chem. Soc. 1999, 121, 250.
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See S. J. Davies, J. A. K. Howard, R. J. Musgrove, F. G. A. Stone, Angew. Chem. 1989, 101, 613; Angew. Chem. Int. Ed. Engl. 1989, 28, 624, and references therein.
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Typically four-membered Os-Sn-Os-Sn cycles are formed, but recently also a hexameric species containing a 12-membered ring made of alternating Os-Sn metal atoms has been isolated: see W. K. Leog, R. K. Pomeroy, R. J. Batchelor, F. W. B. Einstein, C. F. Campana Organometallics, 1997, 16, 1079, and references therein.
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85037446773
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2Re system of 1 by one Re(μ-H)Re interaction and the formation of terminal Re-X and Re-H bonds. This could explain the much more favorable thermodynamics of this step. In the other steps, one terminal hydride is already present in the incoming nucleophile (and it becomes a bridging one in the reaction product, see Scheme 9).
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85037473338
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4 fragment shows a 2:1:1 pattern of the CO resonances, indicating the dynamic averaging of the trans-diaxial carbonyls.
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