Reactions of (1-diazo-2-oxoalkyl)silanes with 3H-1,2,3,4- triazaphospholes: A route to short-lived 4-imino-1,2,4 (λ5)-diazaphospholes

Tetrahedron

Volumn 56, Issue 1, 2000, Pages 35-42

  Kerth, Jochen ^a   Werz, Udo ^a   Maas, Gerhard ^a  

^a UNIVERSITY OF ULM   (Germany)

Author keywords

Cycloadditions; Diazo compounds; Phosphine imines; Phosphorus heterocycles

Indexed keywords

3 (1 ADAMANTYL) 5 (2,2 DIMETHYLPROPANOYL) 4 ETHOXY 4 ISOCYANATO 1 TRIISOPROPYLSILYL 1,2,4 LAMBDA5 DIAZAPHOSPHOLE; 4,11 DI(TERT BUTYL) 1,8 DI(2,2 DIMETHYLPROPANOYL) 6,12 DIPHENYL 2,9 DI(TRIISOPROPYLSILYL) 2,3,6,9,10,12 HEXAAZA 5 LAMBDA5,7 LAMBDA5 DIPHOSPHADISPIRO[4.1.4.1]DODECA 1(5),3,7,10 TETRAENE; PHOSPHOLE DERIVATIVE; UNCLASSIFIED DRUG;

CONFERENCE PAPER; CRYSTAL STRUCTURE; ORGANIC CHEMISTRY; PRIORITY JOURNAL; REACTION ANALYSIS; STRUCTURE ANALYSIS; X RAY ANALYSIS;

EID: 0033965150     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(99)00770-X     Document Type: Conference Paper

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34. The crystal structures were solved and refined with the program package SHELX-97 (Sheldrick, G. M., University of Göttingen, 1997). Molecule plots were made with ORTEP-3 for Windows (Farrugia, L. J., University of Glasgow, 1998).
35. The crystal structures were solved and refined with the program package SHELX-97 (Sheldrick, G. M., University of Göttingen, 1997). Molecule plots were made with ORTEP-3 for Windows (Farrugia, L. J., University of Glasgow, 1998).
36. Crystallographic data (excluding structure factors) for the X-ray crystal structure analyses reported in this paper have been deposited with the Cambridge Crystallographic Data Centre. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: +44-1223-336-033, e-mail: deposit@ccdc.cam.ac.uk).