Two proton positions in the very strong hydrogen bond of serandite, NaMn2[Si3O8(OH)]

American Mineralogist

Volumn 85, Issue 5-6, 2000, Pages 745-752

  Jacobsen, Steven D ^a,b   Smyth, Joseph R ^a,b   Swope, R Jeffrey ^a   Sheldon, Robert I ^c  

^a UNIVERSITY OF COLORADO   (United States)

^b UNIVERSITÄT BAYREUTH   (Germany)

^c LOS ALAMOS NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BOND LENGTH; CRYSTAL STRUCTURE; NEUTRON DIFFRACTION; SILICON COMPOUNDS; SINGLE CRYSTALS; X RAYS;

AMBIENT CONDITIONS; ASYMMETRIC HYDROGEN BONDS; DOUBLE WELL; HYDROGEN POSITIONS; NEUTRON DIFFRACTION DATA; STRUCTURE CORRELATIONS; STRUCTURE DATA; TIME OF FLIGHT;

HYDROGEN BONDS;

CRYSTAL STRUCTURE; HYDROGEN; SERANDITE; SPECTROSCOPY;

EID: 0033946887     PISSN: 0003004X     EISSN: None     Source Type: Journal    
DOI: 10.2138/am-2000-5-613     Document Type: Article

References (30)

1. 2- unit. Mineralogy and Petrology, 61, 223-235.
2. Bergerhoff, G., Hundt, R., Sievers, R., and Brown, I.D. (1983) ICSD, Inorganic Crystal Structure Database. Journal of Chemical Information and Computer Sciences, 23, 66-69.
3. Becker, P.J. and Coppens, P. (1974) Extinction within the limit of validity of the Darwin Transfer Equations I: General formalisms for primary and secondary extinction and their application to spherical crystals. Acta Crystallographica, A30, 129-147.
4. Borkowski, C.J. and Kopp, M.J. (1978) Recent improvements to R-C line encoded position-sensitive proportional counters. Journal of Applied Crystallography, 11, 430-434.
5. 9. Zeitschrift für Kristallographie, 108, 248-262.
6. Emsley, J. (1981) Very strong hydrogen bonding. Chemical Society Reviews, 9, 91-124.
7. Gibbs, G.V. (1982) Molecules as models for bonding in silicates. American Mineralogist, 67, 421-450.
8. Finney J.L. (1995) The complementary use of X-ray and neutron diffraction in the study of crystals. Acta Crystallographica, B51, 447-467.
9. 8(OH)]. American Mineralogist, 83, 569-576.
10. Hofmeister, A.M., Cynn, H., Burnley, P.C., and Meade, C. (1999) Vibrational spectra of dense, hydrous magnesium silicates at high pressure: Importance of the hydrogen bond angle. American Mineralogist, 84, 454-464.
11. Kuroda, Y., Suzuoki, T., and Matsuo, S. (1979) The lowest dD value found in a hydrous silicate, pectolite. Nature, 279, 227-228.
12. Libowitzky, E. (1999) Correlation of O-H stretching frequencies and O-H⋯O hydrogen bond lengths in minerals. Monatshefte für Chemie, 130, 1047-1059.
13. Larson, A.C. and Von Dreele, R.B. (1994) Los Alamos National Laboratory, General Structure Analysis System (GSAS). LA-UR 86-748. Los Alamos, New Mexico.
14. Lutz, H.D. (1995) Hydroxide ions in condensed materials - correlation of spectroscopic and structural data. Structure and Bonding, 82, 85-103.
15. Mikenda, W. (1986) Stretching frequency versus bond distance correlation of O-D(H)⋯Y (Y = N, O, S, Se, Cl, Br, I) hydrogen bonds in solid hydrates. Journal of Molecular Structure, 147, 1-15.
16. Nakamoto, K., Margoshes, M., and Rundle R.E. (1955) Stretching frequencies as a function of distance in hydrogen bonds. Journal of the American Chemical Society, 77, 6480-6488.
17. Novak, A. (1974) Hydrogen bonding in solids. Correlation of spectroscopic and crystallographic data. Structure and Bonding, 18, 177-216.
18. Nyfeler, D. and Armbruster, T. (1998) Silanol groups in minerals and inorganic compounds. American Mineralogist, 83, 119-125.
19. 9. Geological Society of America, Abstracts with Program, 8, 1034.
20. Ohashi, Y. and Finger, L.W. (1978) The role of octahedral cations in pyroxenoid crystal chemistry. I. Bustamite, wollastonite, and the pectolite-schizolite-serandite series. American Mineralogist, 63, 274-288.
21. Pauling, L. (1980) The nature of silicon-oxygen bonds. American Mineralogist, 65, 321-323.
22. 9. Zeitschrift für Kristallographie, 125, 298-316.
23. Prewitt, C.T. and Buerger, M.J. (1963) Comparison of the crystal structures of wollastonite and pectolite. Mineralogical Society of America, Special Paper, 1, 293-302.
24. Robinson, K., Gibbs, G.V., and Ribbe, P.H. (1971) Quadratic elongation: A quantitative measure of distortion in coordination polyhedra. Science, 172, 567-570.
25. Sheldrick, G. (1990) SHELXTL-PC (Release 4.1), 296 p. Siemens Analytical X-ray Instruments, Inc., Madison, Wisconsin.
26. 4: A potential host for water in the mantle? American Mineralogist, 72, 1051-1055.
27. _(1989) Electrostatic characterization of oxygen sites in minerals. Geochemica et Cosmochimica Acta, 53, 1101-1110.
28. Smyth, J.R. and Clayton, R.N. (1988) Correlation of oxygen isotope fractionation and electrostatic site potentials in silicates. Transactions, American Geophysical Union, Program with Abstracts, 69, 1514.
29. Takéuchi, Y. and Kudoh, Y. (1977) Hydrogen bonding and cation ordering in Magnet Cove pectolite. Zeitschrift für Kristallographie, 146, 281-292.
30. Takéuchi, Y., Kudoh, Y., and Yamanaka, T. (1976) Crystal chemistry of the serandite pectolite series and related minerals. American Mineralogist, 61, 229-237.